ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
Use of Crown Ether Functions as Secondary Coordination Spheres for the Manipulation of Ligand-Metal Intramolecular Electron Transfer in Copper-Guanidine Complexes.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Synthetic approaches to metal-coordination-directed macrocyclic complexes.Frontiers in chemistry · 2022Review
- Switching from Metal- to Ligand-Based Oxidation in Cobalt Complexes with Redox-Active Bisguanidine Ligands.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Stimulation of Redox-Induced Electron Transfer by Interligand Hydrogen Bonding in a Cobalt Complex with Redox-Active Guanidine Ligand.Angewandte Chemie (International ed. in English) · 2021Article
- Use of Crown Ether Functions as Secondary Coordination Spheres for the Manipulation of Ligand-Metal Intramolecular Electron Transfer in Copper-Guanidine Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
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Abstract
Intramolecular electron transfer (IET) between a redox-active organic ligand and a metal in a complex is of fundamental interest and used in a variety of applications. In this work it is demonstrated that secondary coordination sphere motifs can be applied to trigger a radical change in the electronic structure of copper complexes with a redox-active guanidine ligand through ligand-metal IET. Hence, crown ether functions attached to the ligand allow the manipulation of the degree of IET between the guanidine ligand and the copper atom through metal encapsulation.
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