Evidence map›Paper›PMID 35345533›Full record

ArticleJournal of molecular structure2022

New bis hydrazone: Synthesis, X-ray crystal structure, DFT computations, conformational study and

Abdelkader Tabbiche, Abdelaziz Bouchama, Nadjib Chafai, Farouk Zaidi, Chaabane Chiter, Messaoud Yahiaoui, Abdellah Abiza

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In one paragraph

Article in Journal of molecular structure, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
4.4field-weighted citation impact, top 5% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 41 citations in OpenAlex.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 1 institution in 1 country.

Abdelkader TabbicheLaboratoire de Chimie, Ingénierie Moléculaire et Nanostructures, Université Ferhat Abbas Sétif 1, Sétif 19000, Algeria.
Abdelaziz BouchamaDépartement de chimie, Faculté des sciences, Université Ferhat Abbas-Sétif-1, Algeria.
Nadjib ChafaiDepartment of Process Engineering, Faculty of Technology, Laboratory of Electrochemistry of Molecular Materials and Complex (LEMMC). University of Ferhat ABBAS Setif-1, El-Mabouda campus, Sétif 19000, Algeria.
Farouk ZaidiDépartement de chimie, Faculté des sciences, Université Ferhat Abbas-Sétif-1, Algeria.
Chaabane ChiterDepartment of Process Engineering, Faculty of Technology, Laboratory of Electrochemistry of Molecular Materials and Complex (LEMMC). University of Ferhat ABBAS Setif-1, El-Mabouda campus, Sétif 19000, Algeria.
Messaoud YahiaouiDepartment of Process Engineering, Faculty of Technology, Laboratory of Electrochemistry of Molecular Materials and Complex (LEMMC). University of Ferhat ABBAS Setif-1, El-Mabouda campus, Sétif 19000, Algeria.
Abdellah AbizaLaboratoire de Chimie, Ingénierie Moléculaire et Nanostructures, Université Ferhat Abbas Sétif 1, Sétif 19000, Algeria.
University Ferhat Abbas of Setif · DZ

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The aim of this work was to synthesize new bis hydrazone derived from benzil in good yield, namely: (1Z,2Z)-1,2-bis (3-Chlorophenyl Hydrazino) Benzil, encoded by 3-Cl BHB. The benzil (or 1,2-diphenyl ethanedione) reacts with 3-Cl phenyl hydrazine by reflux method using ethanol as solvent to obtain the target compound. The obtained product is depicted by UV-Vis, IR spectroscopy and XRD-crystals analysis. All various contacts intra and intermolecular found in 3-Cl BHB were determined by the X-ray diffraction technique performed on single crystals. On the other hand, the optimized geometric structure of 3-Cl BHB was computed by the DFT/B3LYP method with 6-31 G (d, p) level. So, the bond lengths and angles, frontier molecular orbitals (FMO), surface electrostatic potential of the molecule (MEP), global reactivity descriptors, Mulliken atomic charges, computed vibrational analysis and electronic absorption spectrum were determined to get a good understanding of the electronic properties and the active sites of 3-Cl BHB, then to compare them with experimental data. Additionally, a conformational study was carried out using the same method (DFT). The structure-activity relationships established through molecular docking studies showed that 3-Cl BHB structure strongly binds to the receptors M

Indexed as

Bis hydrazoneConformational studyCOVID-19DFTMolecular dockingXRD

Identifiers

PMID35345533
PMCPMC8934244
OpenAlexW4220856485

What Socratic holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.