Evidence map›Paper›PMID 35726006›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Site-Selective Coordination Assembly of Dynamic Metal-Phenolic Networks.

Wanjun Xu, Shuaijun Pan, Benjamin B Noble, Jingqu Chen, Zhixing Lin, Yiyuan Han, Jiajing Zhou, Joseph J Richardson, Irene Yarovsky, Frank Caruso

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.

0numbers the graph read from it
0cells of the map it votes in
19citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

19 citing papers in PubMed.

  1. Review
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  16. Direct Assembly of Metal-Phenolic Network Nanoparticles for Biomedical Applications.Angewandte Chemie (International ed. in English) · 2023
    Article
  17. Article
  18. Article
  19. Site-Selective Coordination Assembly of Dynamic Metal-Phenolic Networks.Angewandte Chemie (International ed. in English) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Wanjun XuDepartment of Chemical Engineering, The University of Melbourne, Parkville, Victoria, 3010, Australia.ORCID 0000-0003-1023-4671
Shuaijun PanDepartment of Chemical Engineering, The University of Melbourne, Parkville, Victoria, 3010, Australia.ORCID 0000-0001-6370-2470
Benjamin B NobleSchool of Engineering, RMIT University, Melbourne, Victoria, 3001, Australia.ORCID 0000-0003-1332-6117
Jingqu ChenDepartment of Chemical Engineering, The University of Melbourne, Parkville, Victoria, 3010, Australia.ORCID 0000-0002-0950-1923
Zhixing LinDepartment of Chemical Engineering, The University of Melbourne, Parkville, Victoria, 3010, Australia.ORCID 0000-0001-9372-3424
Yiyuan HanDepartment of Chemical Engineering, The University of Melbourne, Parkville, Victoria, 3010, Australia.ORCID 0000-0002-4547-3368
Jiajing ZhouDepartment of Chemical Engineering, The University of Melbourne, Parkville, Victoria, 3010, Australia.ORCID 0000-0001-5203-4737
Joseph J RichardsonDepartment of Materials Engineering, The University of Tokyo, Tokyo, 113-8656, Japan.ORCID 0000-0001-8618-4127
Irene YarovskySchool of Engineering, RMIT University, Melbourne, Victoria, 3001, Australia.ORCID 0000-0002-4033-5150
Frank CarusoDepartment of Chemical Engineering, The University of Melbourne, Parkville, Victoria, 3010, Australia.ORCID 0000-0002-0197-497X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Coordination states of metal-organic materials are known to dictate their physicochemical properties and applications in various fields. However, understanding and controlling coordination sites in metal-organic systems is challenging. Herein, we report the synthesis of site-selective coordinated metal-phenolic networks (MPNs) using flavonoids as coordination modulators. The site-selective coordination was systematically investigated experimentally and computationally using ligands with one, two, and multiple different coordination sites. Tuning the multimodal Fe coordination with catechol, carbonyl, and hydroxyl groups within the MPNs enabled the facile engineering of diverse physicochemical properties including size, selective permeability (20-2000 kDa), and pH-dependent degradability. This study expands our understanding of metal-phenolic chemistry and provides new routes for the rational design of structurally tailorable coordination-based materials.

Indexed as

MetalsPhenolsLigandsLigandsMetalsPhenolsFlavonoidsMetal-Organic FrameworksMicrocapsulesSite-Selective AssemblySupramolecular Chemistry

Identifiers

PMID35726006
PMCPMC9546505

What Socratic holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.