Evidence map›Paper›PMID 35733673›Full record

ArticleRSC advances2022

Deactivation of catalysts in simultaneous reversible and irreversible parahydrogen NMR signal enhancement, and the role of co-ligands in the stabilization of the reversible method.

Adam Mames, Sylwia Jopa, Mariusz Pietrzak, Tomasz Ratajczyk

Abstract read
In one paragraph

Article in RSC advances, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Adam MamesInstitute of Physical Chemistry, Polish Academy of Sciences Kasprzaka 44/52 Warsaw 01-224 Poland tratajczyk@ichf.edu.pl.
Sylwia JopaFaculty of Chemistry, University of Warsaw Pasteura 1 Warsaw 02-093 Poland.
Mariusz PietrzakInstitute of Physical Chemistry, Polish Academy of Sciences Kasprzaka 44/52 Warsaw 01-224 Poland tratajczyk@ichf.edu.pl.ORCID https://orcid.org/0000-0002-0419-5613
Tomasz RatajczykInstitute of Physical Chemistry, Polish Academy of Sciences Kasprzaka 44/52 Warsaw 01-224 Poland tratajczyk@ichf.edu.pl.ORCID https://orcid.org/0000-0003-1613-6933

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Signal Amplification by Reversible Exchange (SABRE) and hydrogeneable Parahydrogen Induced Polarization (hPHIP) can enhance weak NMR signals, and thus increase the range of NMR applications. Here, using an N-heterocyclic carbene Ir-based catalyst, simultaneous SABRE and hPHIP was achieved for the compound with an N-donor site and an acetylene triple bond. It was demonstrated that the interplay between SABRE and hPHIP can be manipulated. Specifically, it was found that the hPHIP effect could be almost completely suppressed, while stable SABRE was observed in subsequent consecutive experiments. The presented results have the potential to increase the numbers of parahydrogen hyperpolarizable molecules.

Identifiers

PMID35733673
PMCPMC9136854

What Socratic holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.