ArticleNano letters2022
Nanoscale Mechanism of Moisture-Induced Swelling in Wood Microfibril Bundles.
Article in Nano letters, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed, 77 citations in OpenAlex.
- Property Variations of Binder-Free Lignin-Rich Fiber Networks Driven by Forming Processes and Hot Pressing.ACS omega · 2026Article
- Atomic Structure of Phosphorylated Nanocellulose Revealed by Dynamic Nuclear Polarization-Enhanced Solid-State NMR.Journal of the American Chemical Society · 2026Article
- Role of Lignin in Hot-Pressing of Paper: Insights from Molecular Simulations and Experiments.Biomacromolecules · 2025Article
- Genetic Impacts on the Structure and Mechanics of Cellulose Made by Bacteria.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Uniform elementary fibrils in diverse plant cell walls.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- Hygroscopic movements of cone scale of white firFrontiers in plant science · 2025Article
- The molecular architecture distinctions between compression, opposite and normal wood ofFrontiers in plant science · 2025Article
- Critical comment on the assumptions leading to 24-chain microfibrils in wood.Nature plants · 2024Article
- Structure and growth of plant cell walls.Nature reviews. Molecular cell biology · 2024Review
- Three-dimensional printing of wood.Science advances · 2024Article
- Diffusion in intact secondary cell wall models of plants at different equilibrium moisture content.Cell surface (Amsterdam, Netherlands) · 2023Article
- Understanding Nanocellulose-Water Interactions: Turning a Detriment into an Asset.Chemical reviews · 2023Review
- Spatioselective surface chemistry for the production of functional and chemically anisotropic nanocellulose colloids.Journal of materials chemistry. A · 2022Review
Corrections and comments
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Authors and funding
5 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Understanding nanoscale moisture interactions is fundamental to most applications of wood, including cellulosic nanomaterials with tailored properties. By combining X-ray scattering experiments with molecular simulations and taking advantage of computed scattering, we studied the moisture-induced changes in cellulose microfibril bundles of softwood secondary cell walls. Our models reproduced the most important experimentally observed changes in diffraction peak locations and widths and gave new insights into their interpretation. We found that changes in the packing of microfibrils dominate at moisture contents above 10-15%, whereas deformations in cellulose crystallites take place closer to the dry state. Fibrillar aggregation is a significant source of drying-related changes in the interior of the microfibrils. Our results corroborate the fundamental role of nanoscale phenomena in the swelling behavior and properties of wood-based materials and promote their utilization in nanomaterials development. Simulation-assisted scattering analysis proved an efficient tool for advancing the nanoscale characterization of cellulosic materials.
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