ArticleAngewandte Chemie (International ed. in English)2022
α-Thianthrenium Carbonyl Species: The Equivalent of an α-Carbonyl Carbocation.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
11 citing papers in PubMed.
- Thianthrenium Salts in Photochemistry.Accounts of chemical research · 2026Article
- Trifluoromethyl Thianthrenium Salts: From Organic Synthesis to Materials.The Journal of organic chemistry · 2026Review
- Synthesis of Acyclic Quaternary α-CFThe Journal of organic chemistry · 2025Article
- Remote difunctionalization of alkenes through a photocatalytically triggered radical clock and α-carbonyl carbocation generation.Communications chemistry · 2025Article
- Red-Light-Mediated Generation of Radicals: Applications in Organic Synthesis, Small-Molecule Activation, Polymerization, and Bio-Related Fields.Angewandte Chemie (International ed. in English) · 2025Review
- Visible-Light-Promoted Synthesis of 1,6-Imino Alcohols by Metal-Free 1,2-Carboimination of Alkenes.Organic letters · 2025Article
- Direct Synthesis of 2-Hydroxytrifluoroethylacetophenones via Organophotoredox-Mediated Net-Neutral Radical/Polar Crossover.The Journal of organic chemistry · 2024Article
- Thianthrene/TfOH-catalyzed electrophilic halogenations usingChemical science · 2024Article
- Visible Light Promotes Cascade Trifluoromethylation/Cyclization, Leading to Trifluoromethylated Polycyclic Quinazolinones, Benzimidazoles and Indoles.Molecules (Basel, Switzerland) · 2022Article
- Organothianthrenium salts: synthesis and utilization.Chemical science · 2022Review
- α-Thianthrenium Carbonyl Species: The Equivalent of an α-Carbonyl Carbocation.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Here we report an α-thianthrenium carbonyl species, as the equivalent of an α-carbonyl carbocation, which is generated by the radical conjugate addition of a trifluoromethyl thianthrenium salt to Michael acceptors. The reactivity allows for the synthesis of C
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.