Evidence map›Paper›PMID 36959098›Full record

ReviewAngewandte Chemie (International ed. in English)2023

Sulfonium Salts as Acceptors in Electron Donor-Acceptor Complexes.

Leendert van Dalsen, Rachel E Brown, James A Rossi-Ashton, David J Procter

Abstract readReview
In one paragraph

Review in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 35 papers.

0numbers the graph read from it
0cells of the map it votes in
35citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

35 citing papers in PubMed.

  1. Article
  2. Iron-Catalyzed Cyclopropanation of Allenes Using Unactivated Alkyl Sulfonium Salts.Angewandte Chemie (International ed. in English) · 2026
    Article
  3. Article
  4. Multicomponent Photochemical Assembly of C(spACS organic & inorganic Au · 2026
    Article
  5. Article
  6. Alkoxysulfonium Salts Unlock Access to New Aryl Sulfonium Salts for Cross-Coupling.Angewandte Chemie (International ed. in English) · 2026
    Article
  7. Article
  8. Article
  9. Article
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  12. Article
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  18. Article
  19. Visible-Light-Mediated Synthesis of AnomericMolecules (Basel, Switzerland) · 2025
    Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Leendert van DalsenDepartment of Chemistry, The University of Manchester, Manchester, UK.
Rachel E BrownDepartment of Chemistry, The University of Manchester, Manchester, UK.
James A Rossi-AshtonDepartment of Chemistry, The University of Manchester, Manchester, UK.ORCID http://orcid.org/0000-0002-0989-2506
David J ProcterDepartment of Chemistry, The University of Manchester, Manchester, UK.ORCID http://orcid.org/0000-0003-3179-2509

Funding

AstraZenecaEngineering and Physical Sciences Research Council
6 · The paper itself

Abstract

The photoactivation of electron donor-acceptor complexes has emerged as a sustainable, selective and versatile strategy for the generation of radical species. Electron donor-acceptor (EDA) complexation, however, imposes electronic constraints on the donor and acceptor components and this can limit the range of radicals that can be generated using the approach. New EDA complexation strategies exploiting sulfonium salts allow radicals to be generated from native functionality. For example, aryl sulfonium salts, formed by the activation of arenes, can serve as the acceptor components in EDA complexes due to their electron-deficient nature. This "sulfonium tag" approach relaxes the electronic constraints on the parent substrate and dramatically expands the range of radicals that can be generated using EDA complexation. In this review, these new applications of sulfonium salts will be introduced and the areas of chemical space rendered accessible through this innovation will be highlighted.

Indexed as

ArylationAryl RadicalCharge TransferEDA ComplexSulfonium Salt

Identifiers

PMID36959098
PMCPMC10952135

What Socratic holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.