Evidence map›Paper›PMID 37296133›Full record

ArticleNature communications2023

An approach to MOFaxanes by threading ultralong polymers through metal-organic framework microcrystals.

Tomoya Iizuka, Hiroyuki Sano, Benjamin Le Ouay, Nobuhiko Hosono, Takashi Uemura

Abstract read
In one paragraph

Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
  2. Article
  3. Reticular Frameworks for Advanced Polymer Materials.Advanced materials (Deerfield Beach, Fla.) · 2026
    Review
  4. Article
  5. Boosting the Strength and Toughness of Polymer Blends via Ligand-Modulated MOFs.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024
    Article
  6. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Tomoya IizukaDepartment of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, 277-8561, Chiba, Japan.
Hiroyuki SanoDepartment of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, Bunkyo-ku, 113-8656, Tokyo, Japan.
Benjamin Le OuayDepartment of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, 277-8561, Chiba, Japan.ORCID http://orcid.org/0000-0001-7053-4786
Nobuhiko HosonoDepartment of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, Bunkyo-ku, 113-8656, Tokyo, Japan. nhosono@g.ecc.u-tokyo.ac.jp.ORCID http://orcid.org/0000-0002-4145-0046
Takashi UemuraDepartment of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, Bunkyo-ku, 113-8656, Tokyo, Japan. uemurat@g.ecc.u-tokyo.ac.jp.ORCID http://orcid.org/0000-0002-1357-3196

Funding

MEXT | Japan Society for the Promotion of Science (JSPS) JP21H00385MEXT | Japan Society for the Promotion of Science (JSPS) JP21H01981MEXT | Japan Society for the Promotion of Science (JSPS) JP21H04687MEXT | Japan Society for the Promotion of Science (JSPS) JP21J12230Ministry of Education, Culture, Sports, Science and Technology (MEXT) JPMXP1122714694
6 · The paper itself

Abstract

Mechanically interlocked architecture has inspired the fabrication of numerous molecular systems, such as rotaxanes, catenanes, molecular knots, and their polymeric analogues. However, to date, the studies in this field have only focused on the molecular-scale integrity and topology of its unique penetrating structure. Thus, the topological material design of such architectures has not been fully explored from the nano- to the macroscopic scale. Here, we propose a supramolecular interlocked system, MOFaxane, comprised of long chain molecules penetrating a microcrystal of metal-organic framework (MOF). In this study, we describe the synthesis of polypseudoMOFaxane that is one of the MOFaxane family. This has a polythreaded structure in which multiple polymer chains thread a single MOF microcrystal, forming a topological network in the bulk state. The topological crosslinking architecture is obtained by simply mixing polymers and MOFs, and displays characteristics distinct from those of conventional polyrotaxane materials, including suppression of unthreading reactions.

Indexed as

CatenanesMetal-Organic FrameworksPolymersCatenanesMetal-Organic FrameworksPolymers

Identifiers

PMID37296133
PMCPMC10256729

What Socratic holds

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LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.