ReviewMolecules (Basel, Switzerland)2023
Advancing Our Understanding of Pyranopterin-Dithiolene Contributions to Moco Enzyme Catalysis.
Review in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Who cites it
8 citing papers in PubMed.
- Computational and Spectroscopic Studies of the Pyrazoline Based Chemosensor for Mo⁶⁺ Detection.Journal of fluorescence · 2026Article
- Accurate Calculation of Electron Paramagnetic Resonance Parameters for Molybdenum Compounds.Chemphyschem : a European journal of chemical physics and physical chemistry · 2025Article
- Molybdenum Cofactor Model Reveals Remarkable Redox Activity at Both Molybdenum and the Pyranopterin Dithiolene Ligand.Journal of the American Chemical Society · 2025Article
- Bond Valence Sum Parameters for Analyzing Pyranopterin Tungsten Enzyme Structures.Molecules (Basel, Switzerland) · 2025Article
- Second-Coordination-Sphere Effects Reveal Electronic Structure Differences between the Mitochondrial Amidoxime Reducing Component and Sulfite Oxidase.Inorganic chemistry · 2024Article
- Active Site Characterization of aInorganic chemistry · 2024Article
- Vinyl-pyrazole as a biomimetic acetaldehyde surrogate.Chemical communications (Cambridge, England) · 2024Article
- The Effect of Selenium-Based Ligands on Tungsten Acetylene Complexes.Inorganic chemistry · 2024Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
The pyranopterin dithiolene ligand is remarkable in terms of its geometric and electronic structure and is uniquely found in mononuclear molybdenum and tungsten enzymes. The pyranopterin dithiolene is found coordinated to the metal ion, deeply buried within the protein, and non-covalently attached to the protein via an extensive hydrogen bonding network that is enzyme-specific. However, the function of pyranopterin dithiolene in enzymatic catalysis has been difficult to determine. This focused account aims to provide an overview of what has been learned from the study of pyranopterin dithiolene model complexes of molybdenum and how these results relate to the enzyme systems. This work begins with a summary of what is known about the pyranopterin dithiolene ligand in the enzymes. We then introduce the development of inorganic small molecule complexes that model aspects of a coordinated pyranopterin dithiolene and discuss the results of detailed physical studies of the models by electronic absorption, resonance Raman, X-ray absorption and NMR spectroscopies, cyclic voltammetry, X-ray crystallography, and chemical reactivity.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.