ArticleChemical science2024
Combining geometric constraint and redox non-innocence within an ambiphilic PBiP pincer ligand.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Phosphorescence of Heavy, T-Shaped Pnictogen Trisamides in Solution at Room Temperature in the Near-Infrared II Region.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Ambiphilic Reactivity and Switchable Methyl Transfer at a T-Shaped Bi(NNN) Complex Enabled by a Redox-Active Pincer Ligand.Journal of the American Chemical Society · 2026Article
- Steric Pruning Unlocks Hierarchical Structuring, Thermochromism, C-H/O Activation, and 6-electron Redox Transmetalation in Planar Bismuth Triamides.Angewandte Chemie (International ed. in English) · 2026Article
- A Crystalline Bismuth(II) Radical Anion: Synthesis, Characterization, and Reactivity.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
4 authors.
Funding
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Abstract
The synthesis of the first pincer ligand featuring a strictly T-shaped group 15 element and its coordination behaviour towards transition metals is described. The platform is itself derived from a trianionic redox non-innocent NNN scaffold. In addition to providing a rigid coordination environment to constrain a Bi centre in a T-shaped geometry to manipulate its frontier molecular orbital constitution, the NNN chelate displays highly covalent bonding towards the geometrically constrained Bi centre. The formation of intriguing ambiphilic Bi-M bonding interactions is demonstrated upon formation of a pincer complex as well as a multimetallic cluster. All compounds are comprehensively characterised by spectroscopic methods including X-ray Absorption Near Edge Structure (XANES) spectroscopy and complemented by DFT calculations.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.