Evidence map›Paper›PMID 38867402›Full record

ArticleChemSusChem2024

Expanding the Use of Benzothioxanthene Imides to Photochemistry: Eco-Friendly Aerobic Oxidation of Sulfides to Sulfoxides.

Stamatis K Serviou, Petros L Gkizis, Darío Puchán Sánchez, Nathan Plassais, Frédéric Gohier, Clement Cabanetos, Christoforos G Kokotos

Abstract read
In one paragraph

Article in ChemSusChem, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Stamatis K ServiouLaboratory of Organic Chemistry, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis, 15771, Athens, Greece.
Petros L GkizisLaboratory of Organic Chemistry, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis, 15771, Athens, Greece.ORCID https://orcid.org/0000-0002-3001-5620
Darío Puchán SánchezCNRS, MOLTECH-ANJOU, SFR-MATRIX, F-49000, Angers, France.
Nathan PlassaisCNRS, MOLTECH-ANJOU, SFR-MATRIX, F-49000, Angers, France.
Frédéric GohierCNRS, MOLTECH-ANJOU, SFR-MATRIX, F-49000, Angers, France.ORCID https://orcid.org/0000-0001-5173-7879
Clement CabanetosCNRS, MOLTECH-ANJOU, SFR-MATRIX, F-49000, Angers, France.ORCID https://orcid.org/0000-0001-7913-376X
Christoforos G KokotosLaboratory of Organic Chemistry, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis, 15771, Athens, Greece.ORCID https://orcid.org/0000-0002-4762-7682

Funding

ANR ANR-20-CE05-0029CNRSHellenic Foundation for Research and Innovation (HFRI) 655
6 · The paper itself

Abstract

The sulfoxide moiety is one of the most commonly utilized groups in pharmaceutical and industrial chemistry. The need for sustainability and easy accessibility to sulfoxide moieties is deemed necessary, due to its ubiquity in natural products and potentially pharmaceutically active compounds. In this context, we report herein a sustainable, aerobic and environmentally friendly photochemical protocol based on the use of a benzothioxathene imide as the photocatalyst to selectively oxidize sulfides under mild irradiation (456 nm), in very low catalyst loading (0.01 mol %) and on water. In addition, to demonstrate the compatibility of our protocol with wide scope of substrates, the latter was successfully applied to the synthesis of the biologically-active Sulforaphane and Modafinil.

Indexed as

AerobicBenzothioxanthene imideOxidationPhotochemistrySulfoxide

Identifiers

PMID38867402
PMCPMC11632559

What Socratic holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.