ArticleAccounts of chemical research2024
Modulating the Photophysical Properties of Twisted Donor-Acceptor-Donor π-Conjugated Molecules: Effect of Heteroatoms, Molecular Conformation, and Molecular Topology.
Article in Accounts of chemical research, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
16 citing papers in PubMed.
- Engineered Framework Photocatalysts for Green HSmall (Weinheim an der Bergstrasse, Germany) · 2026Review
- Luminescent Covalent-Organic Frameworks: Design Strategies, Photophysical Mechanisms, and Applications.Small methods · 2026Review
- Coumarin-Based Hybrids: From Linear Photophysical Properties to Multiphoton Excitation Behavior.ACS physical chemistry Au · 2026Article
- Light-Activated Isolation of High-Quality Mitochondria for Therapeutic Transplantation.Angewandte Chemie (International ed. in English) · 2026Article
- Substrate-Controlled Divergent Reactivity of 2-Alkynylindoles: [2 + 2] Cycloaddition-Retroelectrocyclization versus Tricyanovinylation for the Synthesis of NLOphores.The Journal of organic chemistry · 2026Article
- Red-light-excited dynamic near-infrared organic afterglow materials for in vivo bioimaging.Light, science & applications · 2026Article
- Solar hydrogen production through ambient-pressure seawater splitting.Nature communications · 2026Article
- Dual-State Photophysical Modulation via Bifurcated Hydrogen Bonding in a U-Shaped Dipyridophenazine-Cored Donor-π-Acceptor-π-Donor Fluorophore.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Deuteration Induced Electron-Phonon Coupling Modulation: Suppressing Energy Dissipation and Enhancing Carrier Separation in Organic Photocatalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Excited-state intramolecular charge transfer dynamics in 4-methoxy-4'-nitrostilbene: excitation wavelength and solvent dependence.RSC advances · 2026Article
- Rigid ionic-bonding networks boosting organic room temperature phosphorescence.Nature communications · 2026Article
- Excited-State Relaxation Pathways of 4-Aminobiphenyl-2-Pyrimidine Derivatives: An Ultrafast Perspective.The journal of physical chemistry. A · 2025Article
- Tuning of photophysical, photo- and electrochemical properties of unsymmetrical D-APhotochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2025Article
- Recent Advances in Nano-Drug Delivery Strategies for Chalcogen-Based Therapeutic Agents in Cancer Phototherapy.International journal of molecular sciences · 2025Review
- Nanophotonic-enhanced photoacoustic imaging for brain tumor detection.Journal of nanobiotechnology · 2025Review
- Electrochemical and Optical Properties of D-A-A-A-D Azomethine Triad and Its NIR-Active Polymer.Molecules (Basel, Switzerland) · 2024Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
1 author.
Funding
No grant is acknowledged in the PubMed record.
Abstract
ConspectusModulating the photophysical properties of organic emitters through molecular design is a fundamental endeavor in materials science. A critical aspect of this process is the control of the excited-state energy, which is essential for the development of triplet exciton-harvesting organic emitters, such as those with thermally activated delayed fluorescence and room-temperature phosphorescence. These emitters are pivotal for developing highly efficient organic light-emitting diodes and bioimaging probes. A particularly promising class of these emitters consists of twisted donor-acceptor organic π-conjugated scaffolds. These structures facilitate a spatial separation of the frontier molecular orbitals, which is crucial for achieving a narrow singlet-triplet energy gap. This narrow gap is necessary to overcome the endothermic reverse intersystem crossing process, enhancing the efficiency of thermally activated delayed fluorescence. To precisely modulate the photophysical properties of these emitting materials, it is essential to understand the electronic structures of new donor-acceptor scaffolds, especially those influenced by heteroatoms, as well as their conformations and topologies. This understanding not only improves the efficiency of these emitters but also expands their potential applications in advance technologies.In 2014, the Takeda group made a significant breakthrough by discovering a novel method for synthesizing U-shaped diazaacenes (dibenzo[
Identifiers
What Socratic holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.