ArticleChemical science2024
Core-electron contributions to the magnetic response of molecules with heavy elements and their significance in aromaticity assessments.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
7 citing papers in PubMed.
- The concept of aromaticity after 200 years of benzene.Nature reviews. Chemistry · 2026Review
- Field-induced non-linear magnetic responses of all-metal Jellium σ-aromats.Nature communications · 2026Article
- Craig Excited-State Aromaticity in Metallabenzenes: How, When, and Why?Journal of the American Chemical Society · 2026Article
- Aromaticity in Ancient Zeise's Salt.Inorganic chemistry · 2025Article
- Evaluating Aromaticity in AgChemphyschem : a European journal of chemical physics and physical chemistry · 2025Article
- Planar Tetracoordinate Oxygen Atoms.Angewandte Chemie (International ed. in English) · 2025Article
- Multiconfigurational actinide nitrides assisted by double Möbius aromaticity.Chemical science · 2024Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
This study delves into the magnetic response of core electrons and their influence on the global magnetic response of planar and three-dimensional systems containing heavy elements, employing the removing valence electron (RVE) approximation. We also explore electronic aromaticity indices to understand the potential role of core electrons on electron delocalization in the absence of an external perturbation. The study reveals that core electrons significantly contribute to the overall magnetic response, especially to the magnetic shielding, affecting the interpretation of aromaticity. In contrast, the calculation of the electronic aromaticity indices suggests a negligible participation of the core electrons on electron delocalization. Despite their widespread use, the study emphasizes caution in labeling systems as strongly aromatic based solely on shielding function computations. It is noteworthy to emphasize the limitations associated with each aromaticity criterion; particularly in the context of magnetic shielding function calculations, the core-electron effect contamination is undeniable. Hence, the integration of various criteria becomes imperative for attaining a comprehensive understanding of magnetic responses within complex systems.
Identifiers
What Socratic holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.