ArticleAngewandte Chemie (International ed. in English)2025
Triplet-Sensitized Switching of High-Energy-Density Norbornadienes for Molecular Solar Thermal Energy Storage with Visible Light.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Photocontrolled Isomerization Pathways of Tolylsulfonyl- and Pyrene-Linked Norbornadiene Systems Driven by Absorption Band Targeting.Journal of the American Chemical Society · 2026Article
- Orchestrating photoswitch thermal backconversion using hydrogen bonds to reshape energy landscapes.Nature communications · 2026Article
- Photoinduced Electron Transfer (PET) as Key to Accelerate the Cycloreversion Reaction of Arylquadricyclanes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Molecular Solar Thermal (MOST) Energy Storage-Definitions and Requirements Revisited.Angewandte Chemie (International ed. in English) · 2026Article
- Modulation of Photoluminescence and Solar Thermal Energy Storage in Norbornadiene-Quadricyclane Dimers.Angewandte Chemie (International ed. in English) · 2026Article
- Get a better glimpse on sequential photoreactions of trisnorbornadienes withBeilstein journal of organic chemistry · 2026Article
- Unraveling the Photoisomerization Mechanism of Group-8 Fulvalene-Bridged Bimetallic Complexes for Molecular Solar-Thermal Energy Storage.Journal of the American Chemical Society · 2025Article
- Norbornadiene Quadricyclane as Multimode Photoswitches: Synergistic Light and Protonation-Controlled Heat Release.ChemSusChem · 2025Article
- All-photonic switching of a benzo[Chemical science · 2025Article
- Designing Molecular Solar Thermal Systems Based on the Paternò-Büchi Reaction Coupled to Enzymatic Energy Release.ChemSusChem · 2025Article
- Photoactive Neutral Three-Coordinate Cu(I) Complexes of Anionic N‑Heterocyclic Carbenes.JACS Au · 2025Article
- Triplet-Sensitized Switching of High-Energy-Density Norbornadienes for Molecular Solar Thermal Energy Storage with Visible Light.Angewandte Chemie (International ed. in English) · 2025Article
- Extension of the π-system of monoaryl-substituted norbornadienes with acetylene bridges: influence on the photochemical conversion and storage of light energy.Beilstein journal of organic chemistry · 2024Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Norbornadiene-based photoswitches have emerged as promising candidates for harnessing and storing solar energy, holding great promise as a viable solution to meet the growing energy demands. Despite their potential, the effectiveness of their direct photochemical conversion into the resulting quadricyclanes has room for improvement owing to (i) moderate quantum yields, (ii) poor overlap with the solar spectrum and (iii) photochemical back reactions. Herein, we present an approach to enhance the performance of such molecular solar thermal energy storage (MOST) systems through the triplet-sensitized conversion of aryl-substituted norbornadienes. Our study combines deep spectroscopic analyses, irradiation experiments, and quantum mechanical calculations to elucidate the energy transfer mechanism and inherent advantages of the resulting MOST systems. We demonstrate remarkable quantum yields using readily available sensitizers under both LED and solar light irradiation, significantly surpassing those achieved through direct excitation with photons of higher energy. In contrast to the conventional approach, light-induced back reactions of the high-energy products do not play any role, allowing quantitative switching within minutes. These results not only underscore the potential of triplet-sensitized MOST systems to leverage the high energy storage capabilities of multistate photoswitches but they might also stimulate the broader usage of sensitization strategies in photochemical energy conversion.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.