ArticleNature communications2024
Couple-close construction of non-classical boron cluster-phosphonium conjugates.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The trial behind it
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Who cites it
4 citing papers in PubMed.
- Reimagining o-Carborane-Based Fluorophores: Charge-Transfer from Boron Substituents Triggers Aggregation- and Crystallization-Induced Emission.Angewandte Chemie (International ed. in English) · 2026Article
- Anionic Boron-Cluster BODIPY Conjugates As Promising Photosensitizers for Targeted Antimicrobial Photodynamic Therapy.ACS omega · 2025Article
- Unveiling the True Identity of Carborane-Fused Phosphorus Heterocycles.Organic letters · 2025Article
- Post-coordination of Ru(ii) controlled regioselective B(4)-H acylmethylation ofChemical science · 2025Article
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
Heteropolycyclic molecular systems, which are essential components in the fields of materials and pharmacology, frequently consist of 2D extended organic aromatic rings. Here, we introduce a type of inorganic-organic hybrid 3D conjugates by merging an aromatic boron cluster with a phosphine and a π-conjugated unit. To achieve this, a couple-close synthetic strategy via B-H activation of nido-carboranes with alkynes has been developed, which leads to diverse boron cluster-extended phosphoniums in a twisted structure with high yields under mild conditions. Experimental and theoretical results reveal that the fusion between the boron cluster and the formed borophosphonium heterocycle facilitates electron delocalization throughout the structure. The unusual framework demonstrates distinct properties from bare boron clusters and pure aromatic ring-extended counterparts, such as improved thermal/chemical stability and photophysical properties. Thus, the boron cluster-based 3D conjugates expand the library of aromatic-based heterocyclics, showcasing great potential in functional materials.
Identifiers
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Registered trials
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