Evidence map›Paper›PMID 39610728›Full record

ArticleJACS Au2024

Iridium-Catalyzed Enantioselective Vinylogous and Bisvinylogous Allenylic Substitution.

Sankash Mitra, Santanu Mukherjee

Abstract read
In one paragraph

Article in JACS Au, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Sankash MitraDepartment of Organic Chemistry, Indian Institute of Science, Bangalore560012, India.ORCID https://orcid.org/0000-0002-5159-0763
Santanu MukherjeeDepartment of Organic Chemistry, Indian Institute of Science, Bangalore560012, India.ORCID https://orcid.org/0000-0001-9651-6228

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Compared to the widely explored enol silanes, the applicability of their extended variants especially as bisvinylogous nucleophiles in enantioselective catalysis has been sparse. Herein, we describe the first enantioselective vinylogous and bisvinylogous allenylic substitution using silyl dienol and trienol ethers, respectively, as a nucleophile. With racemic allenylic alcohols as the electrophile, these enantioconvergent reactions are cooperatively catalyzed by an Ir(I)/(phosphoramidite,olefin) complex and Lewis acidic La(OTf)

Identifiers

PMID39610728
PMCPMC11600155

What Socratic holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.