ArticleNature communications2024
Diffusion limited synthesis of wafer-scale covalent organic framework films for adaptative visual device.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
5 citing papers in PubMed.
- Humidity-Guided In Situ Polymerization for Controlled Formation of Smooth, Oriented Covalent Organic Framework Films.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Molecularly Precise Triangular Termination of Kagome Covalent Organic Framework Crystals Enabled by Side-Chain Engineering.Angewandte Chemie (International ed. in English) · 2026Article
- Gas Separation With COF Membranes: Crystalline Design Meets Selective Transport.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
- Molecular Diode-Based Covalent Organic Frameworks: Imine Orientation-Driven Acid-Base Switching Photocatalytic HAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Structural Insights into the Mechanical Behavior of Large-Area 2D Covalent Organic Framework Nanofilms.ACS applied materials & interfaces · 2025Article
Corrections and comments
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Authors and funding
17 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Synthesizing high-crystalline covalent organic framework films is highly desired to advance their applications in two-dimensional optoelectronics, but it remains a great challenge. Here, we report a diffusion-limited synthesis strategy for wafer-scale uniform covalent organic framework films, in which pre-deposited 4,4',4″,4‴-(1,3,6,8-Tetrakis(4-aminophenyl) pyrene is encapsulated on substrate surface with a layer of covalent organic framework prepolymer. The polymer not only prevents the dissolution of precursor, but limits the reaction with terephthalaldehyde dissolved in solution, thereby regulating the polymerization process. The size depends on growth substrates, and 4-inch films have been synthesized on silicon chips. Their structure, thickness, patterning and crystallization degree can be controlled by adjusting building blocks and polymerization chemistries, and molybdenum disulfide have been used as substrates to construct vertical heterostructure. The measurements reveal that using covalent organic framework as a photosensitive layer, the heterojunction displays enhanced photoelectric performance, which can be used to simulate the adaptative function of visual system.
Identifiers
What Socratic holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.