ArticleJournal of the American Chemical Society2025
Iron(III) Complexes with Luminescence Lifetimes of up to 100 ns to Enhance Upconversion and Photocatalysis.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
16 citing papers in PubMed.
- From Molecular Crystals to Electronic Devices: Investigating Structure-Property Relationships of Iron(III) and Cobalt(II) Coordination Complexes.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026Article
- Red light mediated energy transfer catalysisChemical science · 2026Article
- Influence of Transition-Metal Ions on the Photoisomerization of a Pentadentate Azopyridine Ligand: Interplay of Charge-Transfer and Metal-Centered States.Inorganic chemistry · 2026Article
- Excited state distortions reverse the decay lifetime trend in Fe(ii) phenanthroline complexes.Chemical science · 2026Article
- Highly efficient dual-channel doublet emission in lanthanide cerium(III) complex.Light, science & applications · 2026Article
- High-yield visible-to-ultraviolet upconversion by ZnSe quantum dots with dynamic triplet transfer.Nature communications · 2026Article
- Kinetics vs Thermodynamics: Engineering Photoredox Reactivity from an Upper Excited State of FeJournal of the American Chemical Society · 2026Article
- Interplay between ligand field strength and the nephelauxetic effect in chromium(iii) complexes with anionic amido ligands.Chemical science · 2026Article
- Fe(III) complexes with prolonged luminescence lifetimes via excited-state equilibration promoted by reversible intercomponent electron transfer.Nature communications · 2026Article
- Highly-destabilized ligand field excited states of iron carbene complexes and their relation to charge transfer state lifetimes.Chemical science · 2026Article
- Mechanistic Design in Photocatalysis.Accounts of chemical research · 2026Article
- Leveraging Multiproton-Coupled Electron Transfer to Improve Ir(III) Photocatalyst Efficiency.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026Article
- Homomolecular Photon Upconversion in a Perylene-Decorated Iron(III) Complex.Journal of the American Chemical Society · 2025Article
- Beyond Common Energy Transfer: Intramolecular Electron Transfer Cascade Controls Triplet Population of a Long-Lived Iron-Anthracene Molecular Dyad.ACS central science · 2025Article
- Pushing the Thermodynamic and Kinetic Limits of Near-Infrared Emissive CrJournal of the American Chemical Society · 2025Article
- Molecular Design Principles for Photoactive Transition Metal Complexes: A Guide for "Photo-Motivated" Chemists.Journal of the American Chemical Society · 2025Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Iron is the most abundant transition metal element and would be the ideal replacement for noble metals in many applications that rely on luminescent and long-lived electronically excited states. We show that efficient reversible energy transfer between doublet excited states of iron complexes and triplet excited states on organic ligands improves energy storage by up to 350-fold. As a result, luminescence lifetimes of up to 100 ns are achieved, the upconversion from red to blue light becomes 68 times more efficient and the yield of benchmark photoredox reactions is significantly improved. These advances make iron coordination compounds more promising candidates for applications in lighting, solar energy conversion and photocatalysis.
Identifiers
What Socratic holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.