ArticleACS applied materials & interfaces2025
Structural Insights into the Mechanical Behavior of Large-Area 2D Covalent Organic Framework Nanofilms.
Article in ACS applied materials & interfaces, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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Who cites it
2 citing papers in PubMed.
- Humidity-Guided In Situ Polymerization for Controlled Formation of Smooth, Oriented Covalent Organic Framework Films.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Guiding the Design of Multifunctional Covalent Organic Frameworks: High-Throughput Screening of Thermal and Mechanical Properties.Chemistry of materials : a publication of the American Chemical Society · 2025Article
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Two-dimensional covalent organic frameworks (2D COFs) are periodic, permanently porous, lightweight solids with remarkable structural modularity, enabling precise control over their properties. As thin films, they have shown promising applications in chemical separations and organic electronics, making it crucial to understand their stability under mechanical stress. Here, we investigate how two different chemical linkages commonly used for 2D COFs, specifically imine and enamine, influence the mechanical properties of nanoscale thick films. Centimeter-scale 2D COF films with a thickness below 100 nm were synthesized by a condensation reaction at a liquid-liquid interface and subsequently transferred onto patterned substrates for mechanical testing. By employing a custom-made nanotensile testing platform, we achieved a comprehensive mechanical characterization of freestanding 2D COF films over a large area (0.5 mm
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