Evidence map›Paper›PMID 40308949›Full record

ArticleChemical science2025

Post-coordination of Ru(ii) controlled regioselective B(4)-H acylmethylation of

Hou-Ji Cao, Jia-Xin Li, Jia-Hui Yan, Miao-Xin Liu, Qianyi Zhao, Jie Zhang, Ju Zhang, Hong Yan

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Hou-Ji CaoHenan Key Laboratory of Boron Chemistry and Advanced Materials, School of Chemistry and Chemical Engineering, Henan Normal University Xinxiang Henan 453007 P. R. China caohouji@htu.edu.cn zhangju@htu.edu.cn.ORCID https://orcid.org/0000-0002-0539-9124
Jia-Xin LiHenan Key Laboratory of Boron Chemistry and Advanced Materials, School of Chemistry and Chemical Engineering, Henan Normal University Xinxiang Henan 453007 P. R. China caohouji@htu.edu.cn zhangju@htu.edu.cn.
Jia-Hui YanHenan Key Laboratory of Boron Chemistry and Advanced Materials, School of Chemistry and Chemical Engineering, Henan Normal University Xinxiang Henan 453007 P. R. China caohouji@htu.edu.cn zhangju@htu.edu.cn.
Miao-Xin LiuHenan Key Laboratory of Boron Chemistry and Advanced Materials, School of Chemistry and Chemical Engineering, Henan Normal University Xinxiang Henan 453007 P. R. China caohouji@htu.edu.cn zhangju@htu.edu.cn.
Qianyi ZhaoHenan Key Laboratory of Boron Chemistry and Advanced Materials, School of Chemistry and Chemical Engineering, Henan Normal University Xinxiang Henan 453007 P. R. China caohouji@htu.edu.cn zhangju@htu.edu.cn.ORCID https://orcid.org/0000-0002-4113-3155
Jie ZhangHenan Key Laboratory of Boron Chemistry and Advanced Materials, School of Chemistry and Chemical Engineering, Henan Normal University Xinxiang Henan 453007 P. R. China caohouji@htu.edu.cn zhangju@htu.edu.cn.ORCID https://orcid.org/0000-0002-7693-6388
Ju ZhangHenan Key Laboratory of Boron Chemistry and Advanced Materials, School of Chemistry and Chemical Engineering, Henan Normal University Xinxiang Henan 453007 P. R. China caohouji@htu.edu.cn zhangju@htu.edu.cn.
Hong YanState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University Nanjing Jiangsu 210023 P. R. China hyan@nju.edu.cn.ORCID https://orcid.org/0000-0003-3993-0013

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Despite significant progress in the B-H functionalization of carboranes, the development of cost-effective catalytic systems devoid of noble metals, coupled with mechanistic validation of regioselectivity control, remains a formidable challenge. Herein, we disclose an Ag salt-free, redox-neutral, and inexpensive ruthenium(ii)-catalyzed protocol that enables exclusive B(4)-H acylmethylation of

Identifiers

PMID40308949
PMCPMC12038429

What Socratic holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.