ReviewChemical reviews2025
Selective Noncovalent Catalysis with Small Molecules.
Review in Chemical reviews, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
14 citing papers in PubMed.
- Electric-Field Catalysis of Diels-Alder Reactions.ACS central science · 2026Article
- An Enantioselective Alkene Aminoarylation to Form Chiral Indolines via Electrostatically-Directed Palladium Catalysis.Angewandte Chemie (International ed. in English) · 2026Article
- London Dispersion in Confined Chiral Ion-Pair Asymmetric Catalysis: From Background Interaction to Design Principle.Accounts of chemical research · 2026Article
- Atroposelective Bromination for the Synthesis of Chiral Biaryl Phosphines via Cross-Assembled Catalysis with Chiral Phosphoric Acid and Achiral Phenol.Journal of the American Chemical Society · 2026Article
- Chalcogen···π Bonding Catalysis: Concept, Reaction Development and Emerging Opportunities.Chemistry, an Asian journal · 2026Review
- Noncovalent Catalysis of Renewable Chitosan Biopolymer for the Conversion of COACS physical chemistry Au · 2026Article
- Enantioselective Pyrazole Alkylation via Iridium and Squaramide Catalyzed N-H Insertion.Journal of the American Chemical Society · 2026Article
- Article
- Asymmetric Desymmetrizing Sulfonylation of Diarylmethanes via Peptidyl-Cu(I)-Catalysis with Remote Stereocontrol.Journal of the American Chemical Society · 2026Article
- Attractive Noncovalent Interactions versus Steric Confinement in Asymmetric Supramolecular Catalysis.Journal of the American Chemical Society · 2026Article
- Enhanced Selectivity of Chalcogen Bonding over Halogen Bonding Catalyzed C-glycosylation Through Differentiated Intermediate Activation.Angewandte Chemie (International ed. in English) · 2026Article
- Size and Polarizability as Design Principles for Stereoselective Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Review
- Article
- Allylic Amination of Alkenyl Alcohols: Simultaneous Control of Chemoselectivity and Enantioselectivity in Nitrene Transfer Using Ion-Paired Catalysts.ACS catalysis · 2025Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
In catalysis, selectivity reflects the energetic preference for the formation of a single product out of multiple possible reaction outcomes. The classic steric biasing approach in small-molecule catalysis employs steric destabilization of the undesired competing transition states to achieve energetic differentiation. In contrast, enzymes achieve high levels of rate acceleration and selectivity by accelerating the pathway leading to the major product, often through networks of attractive, stabilizing noncovalent interactions. This Review showcases selective noncovalent catalysis (NCC) with small organic molecules and transition-metal complexes. We collect and highlight examples whereby selectivity was documented experimentally to arise from selective stabilization of the transition state leading to the major product. We also showcase how synergistic experimental and computational investigations have enabled the elucidation of specific noncovalent interactions responsible for selective stabilization.
Identifiers
What Socratic holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.