Evidence map›Paper›PMID 40413202›Full record

ArticleNature communications2025

Tracking life and death of carbon nitride supports in platinum-catalyzed vinyl chloride synthesis.

Vera Giulimondi, Mikhail Agrachev, Sergei Kuzin, José Manuel González-Acosta, Andrea Ruiz-Ferrando, Frank Krumeich, Federica Bondino, Yung-Tai Chiang, Matteo Vanni, Gunnar Jeschke and 2 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Vera GiulimondiInstitute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1, 8093, Zürich, Switzerland.
Mikhail AgrachevNCCR Catalysis, Zürich, Switzerland.
Sergei KuzinInstitute of Molecular Physical Science, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1, 8093, Zürich, Switzerland.ORCID http://orcid.org/0000-0001-9133-6973
José Manuel González-AcostaInstitute of Chemical Research of Catalonia (ICIQ-CERCA), Avinguda Països Catalans 16, Tarragona, Spain.ORCID http://orcid.org/0009-0001-4873-6944
Andrea Ruiz-FerrandoInstitute of Chemical Research of Catalonia (ICIQ-CERCA), Avinguda Països Catalans 16, Tarragona, Spain.
Frank KrumeichLaboratory of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1, 8093, Zürich, Switzerland.ORCID http://orcid.org/0000-0001-5625-1536
Federica BondinoConsiglio Nazionale delle Ricerche (CNR), Istituto Officina dei Materiali (IOM), Strada Statale 14 km 163.5, 34149, Basovizza, Italy.ORCID http://orcid.org/0000-0001-6505-9319
Yung-Tai ChiangInstitute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1, 8093, Zürich, Switzerland.ORCID http://orcid.org/0009-0004-9935-4876
Matteo VanniInstitute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1, 8093, Zürich, Switzerland.ORCID http://orcid.org/0000-0002-3657-9638
Gunnar JeschkeNCCR Catalysis, Zürich, Switzerland.ORCID http://orcid.org/0000-0001-6853-8585
Núria LópezInstitute of Chemical Research of Catalonia (ICIQ-CERCA), Avinguda Països Catalans 16, Tarragona, Spain.ORCID http://orcid.org/0000-0001-9150-5941
Javier Pérez-RamírezInstitute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1, 8093, Zürich, Switzerland. jpr@chem.ethz.ch.ORCID http://orcid.org/0000-0002-5805-7355

Funding

Generalitat de Catalunya (Government of Catalonia) FI-1 00437Ministero dell'Istruzione, dell'Università e della Ricerca (Ministry of Education, University and Research) ECS00000041Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (Swiss National Science Foundation) 225147
6 · The paper itself

Abstract

Deactivation of metal-based catalysts for vinyl chloride synthesis via acetylene hydrochlorination is often dictated by indispensable, catalytically-active carbon supports, but underlying mechanisms remain unclear. Carbon nitrides offer an attractive platform for studying them thanks to ordered structure and high N-content, which facilitates coking. Herein, we monitor the life and death of carbon nitride supports for Pt single atoms in acetylene hydrochlorination, demonstrating that specific N-functionalities and their restructuring cause distinct deactivation mechanisms. Varying polymerization and exfoliation degrees in pristine carbon nitrides (i.e., -NH

Identifiers

PMID40413202
PMCPMC12103515

What Socratic holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.