Evidence map›Paper›PMID 40430670›Full record

ArticlePolymers2025

Synthesis and Characterization of Bio-Composite Based on Urea-Formaldehyde Resin and Hydrochar: Inherent Thermal Stability and Decomposition Kinetics.

Bojan Janković, Vladimir Dodevski, Marija Janković, Marija Milenković, Suzana Samaržija-Jovanović, Vojislav Jovanović, Milena Marinović-Cincović

Abstract read
In one paragraph

Article in Polymers, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Bojan Janković"Vinča" Institute of Nuclear Sciences-National Institute of the Republic of Serbia, University of Belgrade, Mike Petrovića Alasa 12-14, P.O. Box 522, 11001 Belgrade, Serbia.
Vladimir Dodevski"Vinča" Institute of Nuclear Sciences-National Institute of the Republic of Serbia, University of Belgrade, Mike Petrovića Alasa 12-14, P.O. Box 522, 11001 Belgrade, Serbia.
Marija Janković"Vinča" Institute of Nuclear Sciences-National Institute of the Republic of Serbia, University of Belgrade, Mike Petrovića Alasa 12-14, P.O. Box 522, 11001 Belgrade, Serbia.
Marija Milenković"Vinča" Institute of Nuclear Sciences-National Institute of the Republic of Serbia, University of Belgrade, Mike Petrovića Alasa 12-14, P.O. Box 522, 11001 Belgrade, Serbia.
Suzana Samaržija-JovanovićDepartment of Chemistry, Faculty of Sciences and Mathematics, University of Priština in Kosovska Mitrovica, 38220 Kosovska Mitrovica, Serbia.ORCID 0000-0003-3642-9741
Vojislav JovanovićDepartment of Chemistry, Faculty of Sciences and Mathematics, University of Priština in Kosovska Mitrovica, 38220 Kosovska Mitrovica, Serbia.ORCID 0000-0002-0446-7762
Milena Marinović-Cincović"Vinča" Institute of Nuclear Sciences-National Institute of the Republic of Serbia, University of Belgrade, Mike Petrovića Alasa 12-14, P.O. Box 522, 11001 Belgrade, Serbia.ORCID 0000-0001-6197-1511

Funding

Ministry of Science, Technological Development and Innovation of the Republic of Serbia 451-03-136/2025-03/200017Ministry of Science, Technological Development and Innovation of the Republic of Serbia 451-03-137/2025-03/200123
6 · The paper itself

Abstract

This work reports a study on the structural characterization, evaluation of thermal stability, and non-isothermal decomposition kinetics of urea-formaldehyde (UF) resin modified with hydrochar (obtained by the hydrothermal carbonization of spent mushroom substrate (SMS)) (UF-HC). The structural characterization of UF-HC, performed by scanning electron microscopy (SEM), Fourier transform infrared (FTIR), and X-ray diffraction analyses, showed that UF-HC consists of a large number of spheroidal particles, which are joined, thus forming clusters. It constitutes agglomerates, which are composed of crystals that have curved plate-like forms, including crystalline UF structure and graphite lattices with an oxidized face (graphene oxide, GO). The measurement of inherent thermal stability and non-isothermal decomposition kinetic analysis was carried out using simultaneous thermogravimetric-differential thermal analyses (TGA-DTA) at various heating rates. Parameters that are obtained from thermal stability assessment have indicated the significant thermal stability of UF-HC. Substantial variation in activation energy and the pre-exponential factor with the advancement of decomposition process verifies the multi-step reaction pathway. The decomposition process takes place through three independent single-step reactions and one consecutive reactions step. The consecutive stage represents a path to the industrial production of valuable heterocyclic organic compounds (furan) and N-heterocyclic compounds (pyrroles), building a green-protocol trail. It was found that a high heating rate stimulates a high production of furan from cellulose degradation via the ring opening step, while a low heating rate favors the production of urea compounds (methylolurea hemiformal (HFn)) by means of methylene ether bridges breaking.

Indexed as

autocatalysisfive-membered aromatic ring compoundsgraphene oxide (GO)kinetic analysispolymer bio-compositethermal reductionthermal stability

Identifiers

PMID40430670
PMCPMC12115115

What Socratic holds

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LicenceCC BY
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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.