Evidence mapPaperPMID 40628372Full record

ArticleOrganic letters2025

Access to 2,5-Disubstituted Thiazoles Via Cyclization of N-Substituted α-Amino Acids.

Hajar Aledwan, Guy Zimmermann, Natalia Fridman, Georgios Vassilikogiannakis, Abed Saady

Abstract read
In one paragraph

Article in Organic letters, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Hajar AledwanDepartment of Chemistry, Bar-Ilan University, Ramat-Gan, 52900, Israel.
Guy ZimmermannDepartment of Chemistry, Bar-Ilan University, Ramat-Gan, 52900, Israel.
Natalia FridmanSchulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa City 3200003, Israel.
Georgios VassilikogiannakisDepartment of Chemistry, University of Crete, Vasilika Vouton, 71003, Iraklion, Crete, Greece.ORCID 0000-0002-9099-383X
Abed SaadyDepartment of Chemistry, Bar-Ilan University, Ramat-Gan, 52900, Israel.ORCID 0000-0002-6142-2376

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We report a mild, metal-free synthesis of 2,5-disubstituted thiazoles from readily available N-substituted α-amino acids. The reaction proceeds via carboxylic acid activation with thionyl chloride, followed by intramolecular cyclization and in situ sulfoxide deoxygenation, affording the target thiazoles in excellent yields. This transition-metal-free, robust, and scalable protocol enables access to a broad range of 2,5-disubstituted thiazoles, bypassing the need for complex reagents and significantly simplifying their synthesis.

Identifiers

PMID40628372
PMCPMC12281621

What Socratic holds

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LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.