ArticleJournal of the American Chemical Society2025
Breaking Kasha's Rule to Enable Higher Reactivity in Photoredox Catalysis.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
18 citing papers in PubMed.
- Beyond photobleaching: radical-driven photocleavage and destaining mechanisms in chromophore-biomolecule conjugates.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2026Review
- Photophysics of Doubly Reduced Quinacridone Dyes: Toward Redox Reactivity Activated by Red Light.Artificial photosynthesis (Washington, D.C.) · 2026Article
- Recent advances in temperature and metastable-state effects on organic long-lived emission.Chemical science · 2026Review
- Gold Quantum Rods: Modulation of Singlet and Triplet Exciton Populations by the Rod Length.Journal of the American Chemical Society · 2026Article
- Metal-Centered Photoredox Catalysis using d6 Transition Metal-based Chromophores.Accounts of chemical research · 2026Article
- Article
- From Fundamental Photophysics to Photocatalysis: Energy Gap Law Analysis of Anion Radical Excited States.ACS central science · 2026Article
- Kinetics vs Thermodynamics: Engineering Photoredox Reactivity from an Upper Excited State of FeJournal of the American Chemical Society · 2026Article
- Beyond the three-state picture: when higher-lying excited states become quantitatively indispensable.Chemical science · 2026Article
- Hot-Carrier Injection and Millisecond Charge Separation from a Robust Heteroleptic Iron(II) Chromophore Immobilized on TiOJournal of the American Chemical Society · 2026Article
- Near-Infrared-Light-Driven Photochemistry and Photocatalysis: Mechanisms, Recent Applications, and Opportunities in Organic Synthesis and Biology.Angewandte Chemie (International ed. in English) · 2026Review
- Mechanistic Design in Photocatalysis.Accounts of chemical research · 2026Article
- Expanding Thermodynamic and Kinetic Frontiers in Molecular Photocatalysis.ACS central science · 2026Review
- Article
- Photoinduced Tautomerisation of ESIPT-Capable Iridium(III) Complexes with Rationally Designed Acyclic Diaminocarbene Ligands.Inorganic chemistry · 2026Article
- Spin-State and Reorganization Energy Considerations for Metal-Centered Photoredox Catalysis.Journal of the American Chemical Society · 2025Article
- Structural Control of Metal-Centered Excited States in Cobalt(III) Complexes via Bite Angle and π-π Interactions.Journal of the American Chemical Society · 2025Article
- Pushing the Thermodynamic and Kinetic Limits of Near-Infrared Emissive CrJournal of the American Chemical Society · 2025Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Nearly all photochemical transformations known to date follow Kasha's rule, implying that reactions occur only from the lowest electronically excited state of a given spin multiplicity due to the fast relaxation of higher-energy states. We challenge this foundational principle by demonstrating with time-resolved laser spectroscopy that the 4,4″-dicyano-
Identifiers
What Socratic holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.