Evidence map›Paper›PMID 40756747›Full record

ReviewACS electrochemistry2025

Beyond Conventional Organic Electrosynthesis: The Role of Fluorinated Solvents.

Xavier Marset, Salvador Montilla-Verdú, Elio Rico, Néstor Guijarro

Abstract readReview
In one paragraph

Review in ACS electrochemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Review
  6. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Xavier MarsetInstitute of Electrochemistry, Universidad de Alicante, Apdo. 99, 3080 Alacant, Spain.ORCID https://orcid.org/0000-0003-4914-2918
Salvador Montilla-VerdúInstitute of Electrochemistry, Universidad de Alicante, Apdo. 99, 3080 Alacant, Spain.ORCID https://orcid.org/0009-0008-7756-0045
Elio RicoInstitute of Electrochemistry, Universidad de Alicante, Apdo. 99, 3080 Alacant, Spain.
Néstor GuijarroInstitute of Electrochemistry, Universidad de Alicante, Apdo. 99, 3080 Alacant, Spain.ORCID https://orcid.org/0000-0002-3277-8816

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Organic electrosynthesis has emerged as a unique platform for chemical manufacturing owing to not only the use of electricity as a green reagent but also, especially, to its distinct reactivity. While conventional solvents are sought to remain inert and solely provide a liquid environment for the electrochemical process to occur, fluorinated alcohol solvents have been shown to redefine this concept. In fact, the singular properties of these solvents allow them to actively interact with the substrates and reaction intermediates driving dramatic changes in the chemo- and regioselectivity as well as on the reaction yields. Given the rapid permeation of these solvents in the burgeoning field of electro-organic synthesis, this mini-review strives to provide a concise but up-to-date critical revision for the growing community of scientists working at the interface of synthetic chemistry and electrochemistry. Here, the main electrosynthetic transformations where they have been exploited besides their key role in activating certain reaction pathways will be highlighted. Finally, a forward-looking perspective on the more practical evolution and implementation of these systems will be discussed.

Indexed as

electrosynthesisfluorinated solventorganic chemistrysolvent effectsustainability

Identifiers

PMID40756747
PMCPMC12312091

What Socratic holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.