Evidence map›Paper›PMID 40847841›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025

Pyrrole-Imine Macrocycle: Self-Organizing Cross-Reactive Anion Receptor and Sensor.

Austin R Sartori, Sandra M George, Aco Radujević, Radek Pohl, Anjusha Prakash, Debmalya Ray, Vyacheslav S Bryantsev, Mikhail Zamkov, Pavel Anzenbacher

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Austin R SartoriChemistry Department, Bowling Green State University, Bowling Green, Ohio, 43403, USA.
Sandra M GeorgeChemistry Department, Bowling Green State University, Bowling Green, Ohio, 43403, USA.
Aco RadujevićChemistry Department, Bowling Green State University, Bowling Green, Ohio, 43403, USA.
Radek PohlInstitute of Organic Chemistry and Biochemistry of the Czech Academy of Science, Prague, 16000, Czech Republic.
Anjusha PrakashChemistry Department, Bowling Green State University, Bowling Green, Ohio, 43403, USA.
Debmalya RayChemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, 37830, USA.
Vyacheslav S BryantsevChemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, 37830, USA.
Mikhail ZamkovDepartment of Physics and Astronomy, Bowling Green State University, Bowling Green, Ohio, 43403, USA.
Pavel AnzenbacherChemistry Department, Bowling Green State University, Bowling Green, Ohio, 43403, USA.

Funding

Bowling Green State UniversityBuilding Strength Award 3300368Compute and Data Environment for ScienceNational Science Foundation NSF CHE 2102581Oak Ridge National Laboratory DE-AC05-00OR22725Office of Science DE-AC05-00OR22725
6 · The paper itself

Abstract

Self-organizing macrocyclic receptor-sensors for phosphorus oxyanions, phosphates, and phosphonates comprising imine moieties were prepared by condensation of dipyrrolylmethane dicarbaldehyde with diethylene triamine. The incorporation of flexible ethylene moieties endows the macrocycle with unprecedented flexibility and ability to accommodate numerous phosphorus oxyanions from orthophosphate to large anions such as ATP or phosphonate glyphosate. The anion binding was elucidated by NMR titrations, low-temperature NMR, and NOESY NMR. The incorporation of dansyl fluorophore enables sensing of anions using the fluorescence signal, whereas the changes in fluorescence intensity, width of the fluorescence band, and position of the maxima are analyte-specific and useful in recognition and identification of eleven different P-oxyanions in water. The affinity (K

Indexed as

anionsfluorescenceglyphosatephosphatesphosphonatessensing

Identifiers

PMID40847841
PMCPMC12520057

What Socratic holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.