ArticleChemical science2025
Azobisheteroarene photoswitches based on isoxazoles and pyrazoles: tunable photostationary states, thermal relaxation and sensitization under confinement.
Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Replacing one or both phenyl moieties of azobenzene with aromatic heterocycles is a versatile strategy to expand molecular diversity and to customize photophysical properties specifically for the intended application. Numerous mono-heteroaryl azo structures have been explored and characterized, with especially arylazopyrazoles (AAPs) and arylazoisoxazoles (AIZ) finding widespread application in various fields such as material science, photopharmacology and supramolecular chemistry. However, bis-heteroaryl motifs have been sparingly explored, with only a handful of examples known to date. Here, we introduce two previously unexplored classes of bisheteroaromatic structures: azobisisoxazole and isoxazoleazopyrazoles. Both classes readily undergo photoisomerization upon irradiation with UV (
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.