Evidence map›Paper›PMID 41001661›Full record

ArticleJACS Au2025

Hidden Carbenes: NHC-Al Species at the Al

Muhammad I Qadir, Camila P Ebersol, Blendo A da Silva, Marcus V Castegnaro, Luciano M Lião, Flávio O Sanches-Neto, Heibbe Cristhian B de Oliveira, Renato B Pontes, Gunter Ebeling, Jairton Dupont

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in JACS Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Muhammad I QadirInstituto de Quimica-Universidade Federal de Goias-UFG, Avenue Esperanca s/n, Câmpus Samambaia, Goiânia, Goias 74690-900, Brazil.
Camila P EbersolInstituto de Quimica-Universidade Federal de Goias-UFG, Avenue Esperanca s/n, Câmpus Samambaia, Goiânia, Goias 74690-900, Brazil.
Blendo A da SilvaInstituto de Quimica-Universidade Federal de Goias-UFG, Avenue Esperanca s/n, Câmpus Samambaia, Goiânia, Goias 74690-900, Brazil.
Marcus V CastegnaroInstitute of Physic, Universidade Federal do Rio Grande do Sul (UFRGS), Avenue Bento Gonçalves, 9500, Porto Alegre, Rio Grande do Sul 91501-970, Brazil.ORCID https://orcid.org/0000-0003-0428-8454
Luciano M LiãoInstituto de Quimica-Universidade Federal de Goias-UFG, Avenue Esperanca s/n, Câmpus Samambaia, Goiânia, Goias 74690-900, Brazil.ORCID https://orcid.org/0000-0001-9985-2980
Flávio O Sanches-NetoInstituto de Quimica-Universidade Federal de Goias-UFG, Avenue Esperanca s/n, Câmpus Samambaia, Goiânia, Goias 74690-900, Brazil.
Heibbe Cristhian B de OliveiraInstituto de Quimica-Universidade Federal de Goias-UFG, Avenue Esperanca s/n, Câmpus Samambaia, Goiânia, Goias 74690-900, Brazil.ORCID https://orcid.org/0000-0002-6937-9982
Renato B PontesInstituto de Fisica-Universidade Federal de Goias-UFG, Avenue, Esperança s/n, Campus Samambaia, Goiânia, Goias 74690-900, Brazil.
Gunter EbelingInstitute of Chemistry-Universidade Federal do Rio Grande do Sul-UFRGS, Avenue Bento Gonçalves, 9500 Porto Alegre, Porto Alegre, Rio Grande do Sul 91501-970, Brazil.
Jairton DupontInstitute of Chemistry-Universidade Federal do Rio Grande do Sul-UFRGS, Avenue Bento Gonçalves, 9500 Porto Alegre, Porto Alegre, Rio Grande do Sul 91501-970, Brazil.ORCID https://orcid.org/0000-0003-3237-0770

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The modification of the surface chemistry of heterogeneous catalysts/supports alters their electronic and catalytic properties, particularly through the incorporation of a monolayer of sophisticated N-heterocyclic carbenes (NHCs). However, the formation of aluminum N-heterocyclic carbene (NHC-Al) goes unrecognized or remains unidentified when imidazolium-based ionic liquids are supported on solids (SILPs). In this work, we identified the formation of NHC-Al species upon the grafting of imidazolium-based ILs onto neutral Al

Indexed as

aluminum N-heterocyclic carbeneselectronic modificationsionic liquids geometrySILPssolid-state NMRs

Identifiers

PMID41001661
PMCPMC12457999

What Socratic holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.