ArticleAngewandte Chemie (International ed. in English)2025
A Crystalline Bismuth(II) Radical Anion: Synthesis, Characterization, and Reactivity.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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Who cites it
5 citing papers in PubMed.
- Phosphorescence of Heavy, T-Shaped Pnictogen Trisamides in Solution at Room Temperature in the Near-Infrared II Region.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Isolation and Reactivity of a Square-Planar Trisamido Silane.Angewandte Chemie (International ed. in English) · 2026Article
- Ambiphilic Reactivity and Switchable Methyl Transfer at a T-Shaped Bi(NNN) Complex Enabled by a Redox-Active Pincer Ligand.Journal of the American Chemical Society · 2026Article
- Steric Pruning Unlocks Hierarchical Structuring, Thermochromism, C-H/O Activation, and 6-electron Redox Transmetalation in Planar Bismuth Triamides.Angewandte Chemie (International ed. in English) · 2026Article
- A Crystalline Bismuth(II) Radical Anion: Synthesis, Characterization, and Reactivity.Angewandte Chemie (International ed. in English) · 2025Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We report the synthesis of a planarized tris-amidobismuthane supported by a rigid, bulky NNN pincer ligand, which enforces a T-shaped geometry at the bismuth center. The Bi(NNN) complex features a low-lying LUMO with distinct Bi(6p) orbital character as shown by DFT calculations. Cyclic voltammetry reveals a fully reversible one-electron reduction at E
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.