ArticleChemistry (Weinheim an der Bergstrasse, Germany)2026
Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth-Ligand Cooperation.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Over the past twenty years, main group chemistry has significantly expanded its scope to include reactivities once considered the exclusive domain of transition metals. Among the emerging concepts, element-ligand cooperation has proven to be a powerful strategy for enabling bond activation reactions but remains relatively unexplored for heavier group 15 elements. In this study, we present a novel class of ylide ligands incorporating additional amino donor sites, specifically designed to promote bismuth-ligand cooperativity. We successfully isolated a series of well-defined bismuth scorpionate complexes supported by these dianionic N,C
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