ReviewRSC advances2025
Structural design of porous organic polymers to mitigate π-stacking-induced quenching in porphyrin/phthalocyanine photosensitizers for enhanced antibacterial activity.
Review in RSC advances, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Authors and funding
6 authors.
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Abstract
Porphyrins and phthalocyanines are cornerstone molecular architectures for photodynamic therapy (PDT), organic photovoltaics, and artificial photosynthesis, prized for their exceptional photophysical properties. However, their extended planar π-conjugated systems inevitably induce aggregation-caused quenching (ACQ) through strong π-π stacking interactions, severely diminishing critical performance metrics like photothermal conversion efficiency and reactive oxygen species (ROS) generation. Porous organic polymers (POPs) have emerged as a transformative platform to overcome this limitation, offering unique capabilities for spatially isolating these photoactive units while maintaining structural integrity and enabling precise porosity control. This comprehensive review systematically analyzes structure-property relationships in porphyrin/phthalocyanine-based POPs. It presents detailed case studies showcasing effective π-stacking suppression strategies and offers forward-looking perspectives for designing next-generation materials optimized for photophysical performance. Key design strategies include host-guest architectures (
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.