Evidence map›Paper›PMID 41427521›Full record

ArticleOrganic letters2026

Harnessing Pnictogen and Chalcogen Bonding for Cross-Electrophile C-P

Gui-Ying Fu, He Sheng, Xiang Li, Xiang-Yu Chen, Yong-Liang Tu, Qiang Liu

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Organic letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Gui-Ying FuBinzhou Institute of Technology, Weiqiao-UCAS Science and Technology Park, Binzhou, Shandong Province 256606, China.
He ShengBinzhou Institute of Technology, Weiqiao-UCAS Science and Technology Park, Binzhou, Shandong Province 256606, China.
Xiang LiSchool of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China.
Xiang-Yu ChenBinzhou Institute of Technology, Weiqiao-UCAS Science and Technology Park, Binzhou, Shandong Province 256606, China.ORCID 0000-0002-0383-0910
Yong-Liang TuSchool of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China.
Qiang LiuSchool of Chemistry and Chemical Engineering, Shandong University of Technology, 266 West Xincun Road, Zibo 255049, China.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

While reductive C-P(III) cross-couplings have proven valuable for the synthesis of triarylphosphines, they often face challenges when applied to triarylphosphines bearing structurally complex aryl groups. Herein, we report an alternative and streamlined reductive C-P(III) cross-coupling strategy, in which aryl sulfonium salts─readily prepared from a wide range of arenes─are directly transformed into triarylphosphines via coupling with chlorophosphines, enabled by pnictogen and chalcogen bonding interactions. Mechanistic investigations further highlight the pivotal role of pnictogen and chalcogen bonding in facilitating the formation of photoactive charge-transfer complexes.

Identifiers

PMID41427521
PMCPMC12797328

What Socratic holds

Textmetadata
LicenceCC BY-NC-ND
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.