Evidence map›Paper›PMID 41457813›Full record

ArticleSmall (Weinheim an der Bergstrasse, Germany)2026

Kinetically Controlled Self-Assembly of a Lipophilic Fluorophore with Phenylalanine-Based Diamides in Artificial Lipid Droplets.

Miku Naruse, Soichiro Ogi, Keiji Kajiwara, Natsumi Fukaya, Yoshikatsu Sato, Masayasu Taki, Shigehiro Yamaguchi

Abstract read
In one paragraph

Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Miku NaruseDepartment of Chemistry, Graduate School of Science, Nagoya University, Nagoya, Japan.
Soichiro OgiIntegrated Research Consortium on Chemical Science (IRCCS), Nagoya University, Nagoya, Japan.ORCID https://orcid.org/0000-0001-5758-2281
Keiji KajiwaraDepartment of Chemistry, Graduate School of Science, Nagoya University, Nagoya, Japan.
Natsumi FukayaDepartment of Chemistry, Graduate School of Science, Nagoya University, Nagoya, Japan.
Yoshikatsu SatoInstitute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Nagoya, Japan.
Masayasu TakiInstitute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Nagoya, Japan.ORCID https://orcid.org/0000-0003-2185-4593
Shigehiro YamaguchiDepartment of Chemistry, Graduate School of Science, Nagoya University, Nagoya, Japan.ORCID https://orcid.org/0000-0003-0072-8969

Funding

Core Research for Evolutional Science and Technology JRMJCR21O5Japan Science and Technology Agency JPMJSP2125Japan Society for the Promotion of Science 22K05079Japan Society for the Promotion of Science 22K21346Japan Society for the Promotion of Science 23K26798Japan Society for the Promotion of Science 24H01710Japan Society for the Promotion of Science 25H01261
6 · The paper itself

Abstract

Lipid droplets (LDs) are vital organelles that govern energy storage and lipid metabolism in cells. The ability to direct the self-assembly of small molecules into defined nanostructures within LDs would provide opportunities to modulate their functions. Although supramolecular polymerization has been extensively investigated in low-polarity media, achieving controlled molecular assembly in neutral lipid droplets remains a formidable challenge. Here, we report the design of a lipophilic donor-acceptor-type fluorophore bearing phenylalanine-derived diamide units, which undergoes controlled supramolecular polymerization in the neutral lipid triolein. In triolein, the molecule assembles into fibrous aggregates that display intense fluorescence and a pronounced Cotton effect in circular dichroism spectrum. Spectroscopic and microscopic analyses reveal that a seeding strategy accelerates the conversion from a kinetically trapped monomeric state to fibrous assemblies. Furthermore, fluorescence imaging in artificial LDs demonstrates that aggregate size can be tuned through the seeding process.

Indexed as

Fluorescent DyesLipid DropletsPhenylalanineCircular DichroismKineticsFluorescent DyesPhenylalaninefluorescence imaginglipophilic fluorophoreseed‐initiated assemblysupramolecular polymerstriolein droplets

Identifiers

PMID41457813
PMCPMC12910420

What Socratic holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.