Evidence map›Paper›PMID 41544128›Full record

ReviewChemical reviews2026

Dynamics of Solvating Water As a Probe of Polymers and Supramolecular Structures.

Willemijn H Boeije, Huib J Bakker

Abstract readReview
In one paragraph

Review in Chemical reviews, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Willemijn H BoeijeAMOLF, Ultrafast Spectroscopy, Science Park 104, 1098 XG Amsterdam, The Netherlands.ORCID 0009-0003-9815-7582
Huib J BakkerAMOLF, Ultrafast Spectroscopy, Science Park 104, 1098 XG Amsterdam, The Netherlands.ORCID 0000-0003-1564-5314

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The (bio)chemical reaction dynamics of polymers and supramolecular systems are intimately related to the conformational dynamics of these systems. A relatively new approach to studying the structure and structural dynamics of large (bio)molecular systems in aqueous solution is the measurement of the dynamics of the solvating water molecules. A suitable technique to measure the reorientation dynamics of solvating water molecules is polarization-resolved femtosecond mid-infrared pump-probe spectroscopy (PR-fs-IR). PR-fs-IR measures the full orientation correlation function of the water molecules in solution and is capable of distinguishing water molecules that are bulk-like and that are in direct (solvation) contact with hydrophobic, hydrophilic, and ionic groups of the solute. In this review, we show how the measurement of the reorientation of the solvating water can provide information on the structures of micelles, water-oil emulsions, and large polymers. We also discuss how the measurement of the water reorientation provides information on the origin of the temperature sensitivity of hydrogels and the folding of proteins. We compare the results obtained with PR-fs-IR with the results obtained with other experimental techniques, such as nuclear magnetic resonance (NMR), terahertz Fourier-transform infrared (THz-FTIR), Raman-multivariate curve resolution (Raman-MCR), dielectric relaxation (DR), and time-resolved optical Kerr effect (OKE) spectroscopy.

Identifiers

PMID41544128
PMCPMC12903760

What Socratic holds

Textmetadata
LicenceCC BY-NC-ND
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.