Evidence mapPaperPMID 41857182Full record

ArticleScientific reports2026

Photocatalytic degradation of polyethylene films using green-synthesized ZnO and Fe

Aminu Shaibu, Jimoh Oladejo Tijani, Ambali Saka Abdulkareem, Sherif Ishola Mustapha, Saheed Mustapha, Isaac Alhamdu Baba

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Article in Scientific reports, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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2 · The registry

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5 · Who and what money

Authors and funding

6 authors.

Aminu ShaibuDepartment of Molecular Biology and Bioinformatics, Africa Centre of Excellence for Mycotoxin and Food Safety, Federal University of Technology, PMB 65, Gidan Kwano Campus, Minna, Niger State, Nigeria.
Jimoh Oladejo TijaniDepartment of Molecular Biology and Bioinformatics, Africa Centre of Excellence for Mycotoxin and Food Safety, Federal University of Technology, PMB 65, Gidan Kwano Campus, Minna, Niger State, Nigeria.
Ambali Saka AbdulkareemDepartment of Molecular Biology and Bioinformatics, Africa Centre of Excellence for Mycotoxin and Food Safety, Federal University of Technology, PMB 65, Gidan Kwano Campus, Minna, Niger State, Nigeria.
Sherif Ishola MustaphaDepartment of Chemical Engineering, University of Ilorin, PMB 1515, Ilorin, Kwara State, Nigeria. mustapha.si@unilorin.edu.ng.
Saheed MustaphaDepartment of Chemistry, Federal University of Technology, PMB 65, Bosso Campus, Minna, Nigeria.
Isaac Alhamdu BabaDepartment of Chemical Engineering, Federal University of Technology, PMB 65, Gidan Kwano Campus, Minna, Niger State, Nigeria.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

This study reports the green synthesis of zinc oxide (ZnO) and iron oxide (Fe3O4) nanoparticles using Acacia nilotica (L.) leaf extract and their application in the photocatalytic degradation of low-density polyethylene (LDPE) and high-density polyethylene (HDPE) films in aqueous medium. Phytochemical screening revealed that A. nilotica leaves contained high levels of phenolics (298.21 mg/100 g) and tannins (53.33 mg/100 g), providing strong reducing and stabilizing agents for nanoparticle formation. The synthesized ZnO and Fe3O4 nanoparticles exhibited UV–Vis absorption peaks at 385.09 and 467.92 nm with corresponding band gaps of 3.22 and 2.65 eV, confirming their semiconducting properties. Dynamic light scattering showed mean particle sizes of 13.64 nm (PDI 0.172) for ZnO and 19.21 nm (PDI 0.309) for Fe3O4, indicating uniform dispersion and good colloidal stability. XRD and HRSEM analyses confirmed their crystalline, well-defined morphologies, while EDX verified elemental purity. BET surface areas of 216.81 m²/g for ZnO and 199.41 m²/g for Fe3O4 suggested mesoporosity suitable for catalytic applications. Photocatalytic degradation studies revealed substantial polyethylene breakdown after 30 days under sunlight, with LDPE weight reduced to 73.07% (ZnO) and 74.90% (Fe3O4), and HDPE reduced to 91.20% and 91.76%, respectively. FTIR spectra of treated films showed the formation of carbonyl, hydroxyl, and C–O functional groups, while SEM images displayed surface cracks and cavities indicative of polymer chain scission. EDX spectra further confirmed Zn and Fe incorporation with intensified oxygen peaks, evidencing oxidative degradation. These findings demonstrate that A. nilotica-mediated ZnO and Fe3O4 nanoparticles are effective and sustainable photocatalysts for polyethylene degradation, offering a promising route toward eco-friendly plastic waste management.

Indexed as

Acacia niloticaGreen synthesisIron oxide nanoparticlesPhotocatalysisPolyethylene degradationZinc oxide nanoparticles

Identifiers

PMID41857182
PMCPMC13139506

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