ArticleChemical science2026
The fine effects of high magnetic fields on hyperfine shifts.
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
1 citing paper in PubMed.
- Generalization of Bleaney's Theory.The journal of physical chemistry. A · 2026Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We report a comprehensive investigation of the magnetic field dependence of NMR hyperfine shifts in paramagnetic systems, a critical observable in the study of molecular magnetism. By combining high-field NMR experiments with quantum chemical calculations, we demonstrate that hyperfine shifts exhibit a measurable dependence on the external field. This dependence arises from the interplay between partial molecular alignment and the nonlinear response of the induced magnetic field to the applied magnetic field. We consistently observe a systematic decrease in shifts at higher fields, indicating that the nonlinear contribution is the dominant mechanism. This effect is particularly strong in lanthanoid complexes, where the relative reduction of the shift is primarily determined by the central metal ion. For transition metals, the field dependence depends on the balance of contact and pseudocontact shifts, providing new constraints to check computational protocols.
Identifiers
What Socratic holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.