ArticleChemical science2026
Synergistic diselenide/guanidine catalyzed dehydrophosphorylation of 2-nitrobenzhydrols to access C-stereogenic phosphinates.
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The development of a catalytic and mild variant of the Atherton-Todd reaction for the synthesis of chiral phosphorus-containing compounds presents substantial challenges. Herein, we report a method for accessing C-stereogenic phosphinates enabled by a synergistic diselenide/chiral guanidine catalytic system. This method avoids stoichiometric halogenating reagents, generating water as the sole byproduct. Mechanistic studies reveal that the electron-deficient diselenide catalyst serves as a recyclable alternative for halogenating agents, while the chiral guanidine activates the alcohol
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