ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Antenna Effect in Halogen-Containing ZnSm Coordination Compounds: Utilizing Colorimetry for a Room-Temperature Tunable Ratiometric Molecular Thermometer.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Temperature-dependent photoluminescence (TDPL) is an efficient optical characterization method. Compared to traditional ratiometric photothermal instruments that rely on doped materials and suffer from poor reproducibility, molecular ratiometric thermometers offer advantages such as high precision, fast response, remote temperature measurement capability, and good optical stability. We synthesized three halogen-substituted bimetallic coordination compounds using a one-pot method, which showed good reproducibility. The molecular complexs are abbreviated as ZnSm-X (X = Cl, Br, I). Importantly, ZnSm-X with different halogen substitutions exhibit different temperature dependencies at 253-333 K. Among them, the ZnSm-Cl has a relative sensitivity of 12.14% K
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