ArticleChemistryOpen2026
Sterically Controlled Interfacial Charge-Transfer Mechanisms in Unsymmetrical Squaraine Dyes for Suppressed Aggregation and Enhanced Performance in High-Efficiency Dye-Sensitized Solar Cells.
Article in ChemistryOpen, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Steric regulation at the dye/semiconductor interface critically governs charge recombination and interfacial energetics in dye-sensitized solar cells (DSSCs) but remains poorly defined for unsymmetrical squaraine sensitizers. Here, two π-extended unsymmetrical squaraine dyes (AQ1 and AQ2) are designed to clarify how alkyl-chain-induced steric modulation influences aggregation, surface packing, and intramolecular charge-transfer (ICT) dynamics. Both dyes show strong visible-near-infrared absorption and suitable the highest occupied molecular orbital and the lowest unoccupied molecular orbital (HOMO-LUMO) alignment for electron injection into TiO
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