Evidence map›Paper›PMID 42095563›Full record

ArticleAngewandte Chemie (International ed. in English)2026

Aziridination of a Single Carbon Atom in Alkenes via Energy Transfer Catalysis.

Fritz Paulus, Corinna Heusel, Felix H Wessels, Bünyamin Sikora, Maik G Niedziella, Kilian van der Beck, Constantin G Daniliuc, Frank Glorius

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Aziridination of a Single Carbon Atom in Alkenes via Energy Transfer Catalysis.Angewandte Chemie (International ed. in English) · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Fritz PaulusOrganisch-Chemisches Institut, Universität Münster, Münster, Germany.
Corinna HeuselOrganisch-Chemisches Institut, Universität Münster, Münster, Germany.
Felix H WesselsOrganisch-Chemisches Institut, Universität Münster, Münster, Germany.
Bünyamin SikoraOrganisch-Chemisches Institut, Universität Münster, Münster, Germany.
Maik G NiedziellaOrganisch-Chemisches Institut, Universität Münster, Münster, Germany.
Kilian van der BeckOrganisch-Chemisches Institut, Universität Münster, Münster, Germany.
Constantin G DaniliucOrganisch-Chemisches Institut, Universität Münster, Münster, Germany.
Frank GloriusOrganisch-Chemisches Institut, Universität Münster, Münster, Germany.ORCID https://orcid.org/0000-0002-0648-956X

Funding

Deutsche Forschungsgemeinschaft GL349/7-2inPriorityProgramSPP2102Deutsche Forschungsgemeinschaft GRK2678-437785492European Research Council 101098156
6 · The paper itself

Abstract

Traditional alkene aziridination relies on the alkene's reaction with a (formal) nitrene species, whereby the alkene provides both carbon atoms for the formed heterocycle. In contrast to this paradigm, we herein report a divergent manifold consisting of intermolecular aziridination at a single alkene site with concomitant functionalization of the second alkene site. This process unlocks alternative chemical space from alkenes through energy transfer-catalyzed difunctionalization of alkenyl boronates and silanes toward spring-loaded imine intermediates and their subsequent facile conversion to an aziridine involving a 1,2-aza-(bora-)Brook rearrangement. The use of visible light and the absence of metals, additional bases, and external heating allow for mild reaction conditions that furnish unprotected and highly substituted aziridines.

Indexed as

alkenyl boronatesaziridinationenergy transfer catalysisNH‐aziridinesregioselective

Identifiers

PMID42095563
PMCPMC13285470

What Socratic holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.