Evidence map›Paper›PMID 42117396›Full record

ArticleInorganic chemistry2026

Isolable Phosphonioacetylides as Strong Neutral Carbon Donors with Variable Steric Demand and Tunable Donor Properties.

Franka Brylak, Liane Perktold, Lucas C Torres, Luis Stechele, Klaus Wurst, Michael Seidl, Christopher B Caputo, Fabian Dielmann

Abstract read
In one paragraph

Article in Inorganic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Franka BrylakInstitute of General, Inorganic and Theoretical Chemistry, Universität Innsbruck, Innsbruck 6020, Austria.ORCID 0000-0003-1590-9324
Liane PerktoldInstitute of General, Inorganic and Theoretical Chemistry, Universität Innsbruck, Innsbruck 6020, Austria.
Lucas C TorresInstitute of General, Inorganic and Theoretical Chemistry, Universität Innsbruck, Innsbruck 6020, Austria.
Luis StecheleInstitute of General, Inorganic and Theoretical Chemistry, Universität Innsbruck, Innsbruck 6020, Austria.
Klaus WurstInstitute of General, Inorganic and Theoretical Chemistry, Universität Innsbruck, Innsbruck 6020, Austria.
Michael SeidlInstitute of General, Inorganic and Theoretical Chemistry, Universität Innsbruck, Innsbruck 6020, Austria.
Christopher B CaputoDepartment of Chemistry, York University, 4700 Keele St, Toronto, Ontario M3J 1P3, Canada.ORCID 0000-0002-7523-0324
Fabian DielmannInstitute of General, Inorganic and Theoretical Chemistry, Universität Innsbruck, Innsbruck 6020, Austria.ORCID 0000-0002-7025-5450

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Phosphonioacetylides are rod-shaped, neutral carbon donors with ambiphilic character at the terminal carbon. Despite their analogy to CO and isocyanides, they remain underexplored due to their high reactivity, and only one isolable free phosphonioacetylide has been reported. Here, we describe two new isolable, room-temperature-persistent examples stabilized either by two N-heterocyclic imines (NHIs) bearing bulky, flexible

Identifiers

PMID42117396
PMCPMC13213908

What Socratic holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.