Evidence map›Paper›PMID 42160060›Full record

ArticleSmall (Weinheim an der Bergstrasse, Germany)2026

Visualizing Metal Nanoparticle Electrochemical Dissolution Atom by Atom.

Pei Zhao, Daniel Houghton, Richard Beanland, Julie V Macpherson

Abstract read
In one paragraph

Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Pei ZhaoDepartment of Chemistry, University of Warwick, Coventry, UK.
Daniel HoughtonDepartment of Chemistry, University of Warwick, Coventry, UK.
Richard BeanlandDepartment of Physics, University of Warwick, Coventry, UK.
Julie V MacphersonDepartment of Chemistry, University of Warwick, Coventry, UK.ORCID https://orcid.org/0000-0002-4249-8383

Funding

China Scholarship Council, University of Warwick (UoW) Scholarship funding programEPSRC Engineered Diamond Technologies programHartnoll Experimental Fuel Technologies Centre
6 · The paper itself

Abstract

Gaining insight into the early stages of the electrochemical dissolution of metal nanoparticles (NPs) provides crucial insights into mechanisms that control this important process. Being able to do this under conditions where atom loss from individual NPs can be quantified is especially challenging. Here, we use identical-location, annular dark field, scanning transmission electron microscopy (IL-ADF-STEM) to provide "time-stamped" snapshots of the dissolution of gold NPs on electron-transparent carbon electrodes. Dissolution is carried out in aqueous chloride (mM) solutions, at anodic potentials, over millisecond timescales. IL-ADF-STEM analysis of the integrated image intensities is employed to estimate the number of atoms within each NP, allowing atom loss (and gain) to be tracked for the same NP, over time, on a particle-by-particle basis. 3D reconstruction of NPs enables changes in 3D morphology to be visualized. Hemispherical-shaped gold NPs ≤4 nm in diameter are interrogated, with the smallest showing the largest atom loss. NPs are revealed to flatten during dissolution, as opposed to a gradual reduction in diameter, and the number of isolated gold atoms on the surface increases. Considerable interactions between NPs also occur, including the formation of single atom bridges and coalescence events. The vertical growth of NPs is also observed.

Indexed as

atomsboron doped diamonddissolutionelectrochemistrygold nanoparticlestransmission electron microscopy

Identifiers

PMID42160060
PMCPMC13275038

What Socratic holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.