Nickel-Catalyzed Cross-Electrophile Coupling of Alkynyl Halides With Allylic Acetates.

Quan Lin, Liping Lin, Yuying Wang, Daohong Yu, Yibao Li, Zhengwang Chen

Abstract read

In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

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0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

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PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Quan LinCollege of Chemistry and Materials Science, Gannan Normal University, Ganzhou, P. R. China.

Liping LinCollege of Chemistry and Materials Science, Gannan Normal University, Ganzhou, P. R. China.

Yuying WangCollege of Chemistry and Materials Science, Gannan Normal University, Ganzhou, P. R. China.

Daohong YuCollege of Chemistry and Materials Science, Gannan Normal University, Ganzhou, P. R. China.ORCID https://orcid.org/0000-0003-4840-9051

Yibao LiCollege of Chemistry and Materials Science, Gannan Normal University, Ganzhou, P. R. China.

Zhengwang ChenCollege of Chemistry and Materials Science, Gannan Normal University, Ganzhou, P. R. China.

Funding

Gannan Normal University BSJJ202306Jiangxi Provincial Double Thousand Plan jxsq2023201001National Natural Science Foundation of China 22301043National Natural Science Foundation of China 22462001National Natural Science Foundation of China 22462002

6 · The paper itself

Abstract

We have developed a Ni-catalyzed cross-electrophile coupling (XEC) strategy that enables the efficient synthesis of diverse skipped enynes from readily accessible alkynyl halides and allylic acetates. This method exhibits broad substrate scope, accommodating a wide range of aliphatic and aromatic electrophiles, as well as complex natural product- and pharmaceutical-derived motifs, which remains a challenge using the current methods. Mechanistic experiments and DFT studies support a double oxidative addition pathway, wherein Ni

Indexed as

alkynyl halidesallyl acetateselectrophilesnickel

Identifiers

PMID42216823

DOI10.1002/anie.5529378

PMCPMC13411486

What Socratic holds

Textmetadata

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.