Evidence map›Paper›PMID 42354380›Full record

ArticleGels (Basel, Switzerland)2026

Effects of a Low-Molecular-Weight Gelator in Vegetable, Mineral Oil and Cocoa Butter: A Comparative Rheological Study.

Emmanuel Anegbe, Cesare Oliviero Rossi, Iolinda Aiello, Nicolas Godbert, Eugenia Giorno, Darren A Makeiff, Pietro Calandra, Paolino Caputo

Abstract read
In one paragraph

Article in Gels (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Emmanuel AnegbeDipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, UdR INSTM della Calabria, Via P. Bucci, Cubo 14/D, 87036 Rende, CS, Italy.ORCID 0000-0002-9503-7994
Cesare Oliviero RossiDipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, UdR INSTM della Calabria, Via P. Bucci, Cubo 14/D, 87036 Rende, CS, Italy.ORCID 0000-0003-4406-7824
Iolinda AielloMAT-InLAB, LASCAMM CR-INSTM, Unità INSTM della Calabria, Dipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, Via P. Bucci 14/C, 87036 Rende, CS, Italy.ORCID 0000-0003-4804-2667
Nicolas GodbertMAT-InLAB, LASCAMM CR-INSTM, Unità INSTM della Calabria, Dipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, Via P. Bucci 14/C, 87036 Rende, CS, Italy.ORCID 0000-0002-5659-8844
Eugenia GiornoMAT-InLAB, LASCAMM CR-INSTM, Unità INSTM della Calabria, Dipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, Via P. Bucci 14/C, 87036 Rende, CS, Italy.
Darren A MakeiffQuantum and Nanotechnologies Research Centre, National Research Council Canada, 11421 Saskatchewan Drive, Edmonton, AB T6G 2M9, Canada.ORCID 0000-0001-9399-3563
Pietro CalandraCNR-ISMN, National Research Council, Institute of Nanostructured Materials, Strada Provinciale 35 D n.9, 00010 Montelibretti, RM, Italy.ORCID 0000-0002-4479-4311
Paolino CaputoDipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, UdR INSTM della Calabria, Via P. Bucci, Cubo 14/D, 87036 Rende, CS, Italy.ORCID 0000-0003-3472-7710

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The demand for eco-friendly viscosity modifiers in food, cosmetics, and lubricants has increased, promoting the development of high-performance, sustainable materials. Low-molecular-weight gelators (LMWGs) are promising candidates, though their behavior in complex systems remains underexplored. In this study, a novel alkylamido isophthalic acid-based LMWG (AIPA-gallic acid) was synthesized. Its performance was evaluated in vegetable oil, mineral oil, and cocoa butter using rheological measurements across varying concentrations and temperatures, with all dynamic rheological measurements conducted in the viscoelastic region. Cacao butter is solid at 15 °C, so the flow curve that can be obtained at this temperature should show high values not comparable with the other liquid oils. No slippage phenomenon was observed. Using a step-rate protocol before acquiring the flow curves, no time-dependent behavior (thixotropy) was observed. Frequency and flow sweep tests were used to assess viscoelastic properties, interaction strength, and coordination number. Results revealed that incorporating AIPA-gallic acid at 4 wt% increased the viscosity by 74 times (at 25 °C) in mineral oil, compared to an increase of about four orders of magnitude in vegetable oil. This suggests the formation of intermolecular interactions that lead to an increased momentum transport process, which is significantly higher in vegetable oil. In contrast, cocoa butter exhibited minimal rheological changes, suggesting that no gelation occurred. Analysis using the weak gel model confirmed that viscosity enhancement arises from a structured network in mineral and vegetable oils, but not in cocoa butter. Temperature-dependent variations in structural parameters further highlight the role of molecular interactions between the gelator and the oil matrix.

Indexed as

isophthalic and gallic acid derivativeslow-molecular-weight gelatororganogelssupergelatorviscosity modifiers

Identifiers

PMID42354380
PMCPMC13298344

What Socratic holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.