Evidence map›Paper›PMID 42445522›Full record

ArticleChemical science2026

Scalable spray-coating of covalent organic framework membranes

Feng Zhang, Zihao Wang, Zhiwen Fan, Jiansong Liu, Chunyue Pan, Shuai Gu, Juntao Tang, Pengpeng Shao, Jiayin Yuan, Guipeng Yu

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Feng ZhangHunan Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University LushanSouth Road 932 Changsha 410083 Hunan P. R. China gilbertyu@csu.edu.cn.
Zihao WangHunan Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University LushanSouth Road 932 Changsha 410083 Hunan P. R. China gilbertyu@csu.edu.cn.
Zhiwen FanHunan Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University LushanSouth Road 932 Changsha 410083 Hunan P. R. China gilbertyu@csu.edu.cn.
Jiansong LiuHunan Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University LushanSouth Road 932 Changsha 410083 Hunan P. R. China gilbertyu@csu.edu.cn.
Chunyue PanHunan Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University LushanSouth Road 932 Changsha 410083 Hunan P. R. China gilbertyu@csu.edu.cn.
Shuai GuHunan Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University LushanSouth Road 932 Changsha 410083 Hunan P. R. China gilbertyu@csu.edu.cn.ORCID https://orcid.org/0000-0001-5322-6976
Juntao TangHunan Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University LushanSouth Road 932 Changsha 410083 Hunan P. R. China gilbertyu@csu.edu.cn.ORCID https://orcid.org/0000-0002-7398-3605
Pengpeng ShaoHunan Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University LushanSouth Road 932 Changsha 410083 Hunan P. R. China gilbertyu@csu.edu.cn.
Jiayin YuanDepartment of Chemistry, Stockholm University SE-10691 Stockholm Sweden.ORCID https://orcid.org/0000-0003-1016-5135
Guipeng YuHunan Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University LushanSouth Road 932 Changsha 410083 Hunan P. R. China gilbertyu@csu.edu.cn.ORCID https://orcid.org/0000-0001-8712-0512

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The scale-up and practical implementation of covalent organic frameworks (COFs) in gas separation remains constrained by intrinsic limitations, including insolubility, infusibility and mismatched pore sizes (>0.8 nm). Drawing inspiration from air-spray principles, herein we develop a facile bottom-up spray-coating strategy for the fabrication of lasagna-like COF membranes for the first time. Theoretical calculations and detailed experiments revealed the core role of spray-coating-induced microdroplet confined assembly, wherein atomized droplets generate spatially confined environments that accelerate molecular ordering and polycondensation. Within these microdroplet-confined spaces, oligo(ethylene glycol) (OEG) side-chains suppress molecular diffusion to enhance crystallization. Such synergy enables dynamic spray cycles to drive COF growth into continuous membranes within 30 minutes. The resulting COF-OEG-4 membrane exhibits outstanding gas separation performance, with an ultrahigh H

Identifiers

PMID42445522
PMCPMC13360833

What Socratic holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the Socratic graph.