ReviewChemistry, an Asian journal2026
Redefining N-Bromosuccinimide: Chemistry Beyond Allylic Bromination.
Review in Chemistry, an Asian journal, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Bromination or subsequent reactions followed by bromination have become easier and more convenient after the invention of N-bromoamides. As a brominating agent, molecular bromine has limitations like decomposition, volatility, high reactivity, and toxicity. Hence, N-bromoamides have emerged as a widely used laboratory reagent for bromination. Among the other N-bromoamides, N-bromosuccinimide (also called NBS) is the most commonly used laboratory reagent. Apart from its most common use in allylic/benzylic bromination and as an electrophilic brominating agent, this reagent has paved its way through various rearrangements, hydrolysis, multicomponent reaction, C─C bond cleavage of β-keto amides, benzylic bromination, stereoselective synthesis, oxidation, catalysis, aromatization, and one-pot tandem reaction. The present review will highlight applications of NBS in organic chemistry apart from bromination. It will focus on how this reagent facilitates various chemical transformations, thereby proving its versatility beyond a mere brominating agent.
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